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The density of vapours of a substance at...

The density of vapours of a substance at 1 atm and 500 K is `0.3 kg m^(-3)`. The vapours effuse 0.4216 times faster than `O_(2)` through a pin hole under identical conditions. If R= 0.08 litre atm `K^(-1) mol^(-1)`. The molar volume of gas is `a xx 10^(2)` litre. The value of a is _____________.

Text Solution

Verified by Experts

The correct Answer is:
6

Let the Mol. Wt. of substance be MO g/mol `:. ("Rate of effusion of substance")/("Rate of effusion of " O_(2)) = sqrt((32)/(M_(0)))`
`rArr (0.4216)^(2) = (32)/(M_(o)) rArr M_(o) = 180g//mol`
As density of substance = 0.3 g/L `:.` Vol. of 1 mole `=(180g//mol)/(0.3g//L) = 600L`
or, `6 xx 10^(2)L`, So, a = 6
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