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The difference between DeltaH and Delta...

The difference between `DeltaH and DeltaU (DeltaH - DeltaU)`, when the combustion of one mole of heptane (l ) is carried out at a temperature T, is equal to: `–xRT`. The value of x is_____.

A

`-4 RT`

B

`4 RT`

C

`-3 RT`

D

`3 RT`

Text Solution

Verified by Experts

The correct Answer is:
A

Heptane, `C_(7)H_(16)(l) + 11 O_(2)(g) rarr 7CO_(2) (g) + 8H_(2) (l)`
Since temperature T is given assume it at room temperature.
`Delta H = Delta U + Delta n(g) RT`
`Delta H - Delta U = -4RT`
`Delta(g) = 7 -11 = -4`
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