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Determine enthalpy change for, C(3)H(8...

Determine enthalpy change for,
`C_(3)H_(8(g))+H_(2(g))rarr C_(2)H_(6(g))+CH_(4(g))`
at `25^(@)C` using heat of combustion values under standard condition.
`{:(Compounds,H_(2(g)),CH_(4(g)),C_(2)H_(6(g)),C_((Graph ite))),(DeltaH^(@)i n kJ//mol,-285.8,-890.0,-1560.0,-393.5):}`
The standard heat of formation of `C_(3)H_(8(g))` is `-103.8 kJ mol^(-1)`.

Text Solution

Verified by Experts

First we need to determine heat of combustion of `C_(3)H_(8)`
`3C(gr) + 4H_(2)(g) rarr C_(3)H_(8)(g) " "Delta H_(f)^(@) = -103 kJ`
`implies -103 kJ = -3 xx 393 - 4 xx 285.80 - Delta_("comb")^(@) (C_3H_8)`
`implies Delta H_("comb")^(@) (C_(3)H_(8)) = -2219.20 kJ`
`implies Delta H_(r )^(@) = sum Delta H_("comb")^(@) ("reactants") - sum DeltaH_("comb")^(@) ("products")`
`= -2219.20 - 285.80 + 1560 + 890 = -55 kJ`.
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