Home
Class 12
CHEMISTRY
An ideal monoatomic gas C(v) = 1.5 R ini...

An ideal monoatomic gas `C_(v) = 1.5 R` initialy at 298 K and `1.013 xx 10^(6)` Pa. pressure expands adiabatically unit it is a in equilibrium with a constant external pressure of `1.013 xx 10^(5)` Pa. Calculate the final temperature of gas.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step-by-step, we will use the principles of thermodynamics and the properties of an ideal monoatomic gas. ### Step 1: Identify the given data - Initial temperature, \( T_i = 298 \, K \) - Initial pressure, \( P_i = 1.013 \times 10^6 \, Pa \) - Final pressure, \( P_f = 1.013 \times 10^5 \, Pa \) - Heat capacity at constant volume for a monoatomic gas, \( C_v = 1.5R \) ### Step 2: Understand the adiabatic process In an adiabatic process, the change in internal energy (\( \Delta U \)) is equal to the work done on the gas. The relationship can be expressed as: \[ \Delta U = -W \] Where \( W \) is the work done by the gas. ### Step 3: Relate internal energy change to temperature For an ideal gas, the change in internal energy can also be expressed as: \[ \Delta U = nC_v(T_f - T_i) \] Where \( n \) is the number of moles of the gas. ### Step 4: Calculate the work done The work done by the gas during expansion against a constant external pressure can be expressed as: \[ W = P_{external} \Delta V = P_f (V_f - V_i) \] ### Step 5: Express volumes in terms of temperature and pressure Using the ideal gas law, we can express the volumes as: \[ V_i = \frac{nRT_i}{P_i} \quad \text{and} \quad V_f = \frac{nRT_f}{P_f} \] Thus, the change in volume \( \Delta V \) can be expressed as: \[ \Delta V = V_f - V_i = \frac{nRT_f}{P_f} - \frac{nRT_i}{P_i} \] ### Step 6: Substitute into the work equation Substituting the expression for \( \Delta V \) into the work equation gives: \[ W = P_f \left( \frac{nRT_f}{P_f} - \frac{nRT_i}{P_i} \right) \] This simplifies to: \[ W = nR(T_f - \frac{P_f}{P_i}T_i) \] ### Step 7: Set up the equation for internal energy change Equating the two expressions for internal energy change: \[ nC_v(T_f - T_i) = -W \] Substituting for \( W \): \[ nC_v(T_f - T_i) = -nR(T_f - \frac{P_f}{P_i}T_i) \] ### Step 8: Cancel \( n \) and rearrange Cancel \( n \) from both sides (assuming \( n \neq 0 \)): \[ C_v(T_f - T_i) = -R(T_f - \frac{P_f}{P_i}T_i) \] Substituting \( C_v = 1.5R \): \[ 1.5R(T_f - T_i) = -R(T_f - \frac{P_f}{P_i}T_i) \] Dividing through by \( R \): \[ 1.5(T_f - T_i) = -(T_f - \frac{P_f}{P_i}T_i) \] ### Step 9: Solve for \( T_f \) Rearranging gives: \[ 1.5T_f - 1.5T_i = -T_f + \frac{P_f}{P_i}T_i \] Combining like terms: \[ 2.5T_f = 1.5T_i + \frac{P_f}{P_i}T_i \] Factoring out \( T_i \): \[ T_f = \frac{T_i(1.5 + \frac{P_f}{P_i})}{2.5} \] ### Step 10: Substitute known values Substituting \( T_i = 298 \, K \), \( P_f = 1.013 \times 10^5 \, Pa \), and \( P_i = 1.013 \times 10^6 \, Pa \): \[ T_f = \frac{298 \left( 1.5 + \frac{1.013 \times 10^5}{1.013 \times 10^6} \right)}{2.5} \] Calculating \( \frac{P_f}{P_i} = \frac{1.013 \times 10^5}{1.013 \times 10^6} = 0.1 \): \[ T_f = \frac{298 \left( 1.5 + 0.1 \right)}{2.5} = \frac{298 \times 1.6}{2.5} \] Calculating: \[ T_f = \frac{476.8}{2.5} = 190.72 \, K \] ### Final Answer The final temperature of the gas is approximately \( T_f \approx 190.7 \, K \).

To solve the problem step-by-step, we will use the principles of thermodynamics and the properties of an ideal monoatomic gas. ### Step 1: Identify the given data - Initial temperature, \( T_i = 298 \, K \) - Initial pressure, \( P_i = 1.013 \times 10^6 \, Pa \) - Final pressure, \( P_f = 1.013 \times 10^5 \, Pa \) - Heat capacity at constant volume for a monoatomic gas, \( C_v = 1.5R \) ...
Promotional Banner

Similar Questions

Explore conceptually related problems

One mole of monoatomic ideal gas at T(K) is exapanded from 1L to 2L adiabatically under constant external pressure of 1 atm . The final tempreture of gas in kelvin is

A gas at 10^(@)C temperature and 1.013xx 10^(5) Pa pressure is compressed adiabatically to half of its volume. If the ratio of specific heats of the gas is 1.4, what is its final temperature?

An ideal gas of volume 2 L is adiabatically compressed to (1//10)^(th) of its initial volume. Its initial pressure is 1.01 xx 105 Pa, calculate the final pressure. (Given gamma = 1.4)

The atmospheric pressure in SI unit I s 1.01 xx 10^(5) Pa. Its value in CGS unit is

One mole of an ideal gas (C_(v,m)=(5)/(2)R) at 300 K and 5 atm is expanded adiabatically to a final pressure of 2 atm against a constant pressure of 2 atm. Final temperature of the gas is :

10 litre of a non linear polyatomic ideal gas at 127^(@)C and 2 atm pressure is suddenly released to 1 atm pressure and the gas expanded adiabatically against constant external pressure. The final temperature and volume of the gas respectively are.

Two mole of ideal diatomic gas (C_("v,m")=5//2R) at 300 K and 5 atm expanded irreversly & adiabatically to a final pressure of 2 atm against a constant pressure of 1 atm. Calculate q, w, DeltaH&DeltaU .