Home
Class 12
CHEMISTRY
The enthalpy of a system increases by 50...

The enthalpy of a system increases by 50 kJ when its internal energy is increased by 113 kJ. What is the pressure in `k Nm^(-2)` of the system if the volume of gas is reduced by `10^(3) m^(3)` at constant pressure?

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will use the relationship between the change in enthalpy (ΔH), the change in internal energy (ΔU), and the change in volume (ΔV) at constant pressure. The equation we will use is: \[ \Delta H = \Delta U + P \Delta V \] ### Step-by-Step Solution: 1. **Identify the Given Values:** - Change in enthalpy, ΔH = 50 kJ - Change in internal energy, ΔU = 113 kJ - Change in volume, ΔV = -1000 m³ (since the volume is reduced) 2. **Convert the Units:** - Convert kJ to J for consistency: - ΔH = 50 kJ = 50,000 J - ΔU = 113 kJ = 113,000 J 3. **Substitute the Values into the Equation:** - Using the equation ΔH = ΔU + PΔV: \[ 50,000 = 113,000 + P(-1000) \] 4. **Rearranging the Equation:** - Rearranging gives: \[ P(-1000) = 50,000 - 113,000 \] \[ P(-1000) = -63,000 \] 5. **Solve for Pressure (P):** - Divide both sides by -1000: \[ P = \frac{-63,000}{-1000} = 63 \text{ kN/m}^2 \] ### Final Answer: The pressure of the system is **63 kN/m²**.

To solve the problem, we will use the relationship between the change in enthalpy (ΔH), the change in internal energy (ΔU), and the change in volume (ΔV) at constant pressure. The equation we will use is: \[ \Delta H = \Delta U + P \Delta V \] ### Step-by-Step Solution: ...
Promotional Banner

Similar Questions

Explore conceptually related problems

When is the heat supplied to a system equal to the increase in its internal energy?

The pressure of a gas at 350K is 2 bar.If the temperature is increased to 500K ,what would be the pressure of the gas if the volume remains constant

When an ideal diatomic gas is heated at constant pressure, its intenal energy is increased by 50cal then the work done by the gas is

When work done by a system was 10J, the increase in the internal energy of the system was 30J. The heat 'q' supplied to the system was:

A system absorbs 50 kJ heat and does 20 kJ of work. What is the net change in the internal energy of the system ?

The change in internal energy in a reaction when 2kJ of heat is released by the system and 6 kJ of work is done on the system will be……

By what percentage should the pressure of a given mass of a gas be increased so as to decrease its volume by 10% at a constant temperature?

What is the change in internal energy when 4 Kj of work is done on the system and 1 Kj of heat is given out.

What is the change in internal energy if 10 J of heat is given to system at constant pressure and 20 J of work is done by the system?