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When 1pentyne (A) is treated with 4N alc...

When `1`pentyne `(A)` is treated with `4N` alcoholic `KOH` at `175^(@)C`, it is slowly converted into an equilibrium mixture of `1.3%` of `1`pentyne `(A), 95.2% 2`-pentyne `(B)` and `3.5%` of `1,2`-pentandiene `(C )`. The equilibrium was maintained at `175^(@)C`. calculate `DeltaG^(Theta)` for the following equilibria:
`B hArr A, DeltaG^(Theta)underset(1) = ?`
`B hArr C, DeltaG^(Theta)underset(2) =?`
From the calculated value of `DeltaG^(Theta)underset(1)`and `DeltaG^(Theta)underset(2)`, indicate the order of stability of `A,B` and `C`.

Text Solution

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`DeltaG_(1)^(@) = 16 kJ, DeltaG_(2)^(@) = 12.3 kJ`
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