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Two solids dissociates as follows A(s) r...

Two solids dissociates as follows
`A(s) rarr B(g) + C(g), K_(P_(1)) = x atm^(2)`
`D(s) rarr C(g) + E(g), K_(P_(2)) = y atm^(2)`
The total pressure when both the solids dissociate simultaneously is :

A

`2(sqrt(x + y))atm`

B

(x + y)atm

C

`(sqrt(x + y))atm`

D

`x^(2) + y^(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the dissociation of the two solids and how they contribute to the total pressure when they dissociate simultaneously. ### Step-by-Step Solution: 1. **Identify the Reactions**: - The first reaction is: \[ A(s) \rightleftharpoons B(g) + C(g) \] with equilibrium constant \( K_{P1} = x \, \text{atm}^2 \). - The second reaction is: \[ D(s) \rightleftharpoons C(g) + E(g) \] with equilibrium constant \( K_{P2} = y \, \text{atm}^2 \). 2. **Establish Partial Pressures**: - Let \( P_1 \) be the partial pressure of \( B \) and \( C \) from the first reaction. - Let \( P_2 \) be the partial pressure of \( E \) from the second reaction. 3. **Relate Partial Pressures to Equilibrium Constants**: - For the first reaction, the equilibrium expression is: \[ K_{P1} = P_B \cdot P_C = P_1 \cdot (P_1 + P_2) = x \] - For the second reaction, the equilibrium expression is: \[ K_{P2} = P_C \cdot P_E = (P_1 + P_2) \cdot P_2 = y \] 4. **Combine the Equations**: - From the first reaction: \[ x = P_1 \cdot (P_1 + P_2) \] - From the second reaction: \[ y = (P_1 + P_2) \cdot P_2 \] 5. **Express Total Pressure**: - The total pressure \( P_{total} \) when both solids dissociate is given by: \[ P_{total} = P_B + P_C + P_E = P_1 + (P_1 + P_2) + P_2 = 2P_1 + P_2 \] 6. **Substitute for \( P_1 + P_2 \)**: - From the combined equations, we can find \( P_1 + P_2 \): \[ P_1 + P_2 = \sqrt{x + y} \] - Thus, substituting this into the total pressure equation: \[ P_{total} = 2P_1 + P_2 = 2\sqrt{x + y} \] ### Final Answer: The total pressure when both solids dissociate simultaneously is: \[ P_{total} = 2\sqrt{x + y} \, \text{atm} \]

To solve the problem, we need to analyze the dissociation of the two solids and how they contribute to the total pressure when they dissociate simultaneously. ### Step-by-Step Solution: 1. **Identify the Reactions**: - The first reaction is: \[ A(s) \rightleftharpoons B(g) + C(g) ...
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