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For the reaction 2SO(2)(g)+O(2)(g)=2SO...

For the reaction
`2SO_(2)(g)+O_(2)(g)=2SO_(3)(g)`
`deltaH=-57.2kJmol^(-1)` and `K_(C)=1.7xx10^(16)` ltbr. Which of the following statements is INCORRECT?

A

The equilibrium constant decreases as the temperature increases

B

The addition of inert gas at constant volume will not affect the equilibrium constant

C

The equilibrium constant is large suggestive of reaction going to completion and so no catalyst is required.

D

The equilibrium will shift in forward direction as the pressure increases

Text Solution

Verified by Experts

The correct Answer is:
C

Given `2SO_(2)(g) + O_(2)(g) rarr 2SO_(2)(g)`
`Delta H = -57.2 KJ//mol`
`Kc = 1.7 xx 10^(16)`
A) From `K darr = Ae^(-DeltaH/RTuarr)` as T increases, K decreases
(B) Equilibrium constant is not a affected by change in volume.
(C) Although Kc is large but it doesn’t mean reaction go for completion.
(D) Equilibrium will shift in forward direction as pressure increases.
Hence (C) is incorrect.
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