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A buffer solution is prepared by mixing ...

A buffer solution is prepared by mixing 0.1 M ammonia and 1.0 M ammonium chloride. At 298 K, the `pK_(b)` of `NH_(4)OH` is 5.0. The pH of buffer is :

A

10

B

9

C

6

D

8

Text Solution

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To find the pH of the buffer solution prepared by mixing 0.1 M ammonia (NH₃) and 1.0 M ammonium chloride (NH₄Cl), we can use the Henderson-Hasselbalch equation. However, since we are given the pK_b value, we will first calculate the pOH and then convert it to pH. ### Step-by-step Solution: 1. **Identify the components of the buffer:** - Base (NH₃): 0.1 M - Salt (NH₄Cl): 1.0 M 2. **Use the given pK_b value:** - pK_b of NH₄OH (which is the same as the conjugate acid of NH₃) = 5.0 3. **Calculate pOH using the formula:** \[ \text{pOH} = \text{pK}_b + \log\left(\frac{[\text{Salt}]}{[\text{Base}]}\right) \] Plugging in the values: \[ \text{pOH} = 5.0 + \log\left(\frac{1.0}{0.1}\right) \] 4. **Calculate the logarithm:** \[ \log\left(\frac{1.0}{0.1}\right) = \log(10) = 1 \] 5. **Substitute back to find pOH:** \[ \text{pOH} = 5.0 + 1 = 6.0 \] 6. **Convert pOH to pH:** Using the relation \( \text{pH} + \text{pOH} = 14 \): \[ \text{pH} = 14 - \text{pOH} = 14 - 6.0 = 8.0 \] ### Final Answer: The pH of the buffer solution is **8.0**.

To find the pH of the buffer solution prepared by mixing 0.1 M ammonia (NH₃) and 1.0 M ammonium chloride (NH₄Cl), we can use the Henderson-Hasselbalch equation. However, since we are given the pK_b value, we will first calculate the pOH and then convert it to pH. ### Step-by-step Solution: 1. **Identify the components of the buffer:** - Base (NH₃): 0.1 M - Salt (NH₄Cl): 1.0 M ...
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