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A strong acid is titrated with weak base...

A strong acid is titrated with weak base. At equivalence point, pH will be :

A

` lt 7`

B

`gt 7`

C

0

D

Cannot predict

Text Solution

AI Generated Solution

The correct Answer is:
To determine the pH at the equivalence point when a strong acid is titrated with a weak base, we can follow these steps: ### Step 1: Understand the Reaction In this titration, we are mixing a strong acid (like HCl) with a weak base (like NH₃). At the equivalence point, all the strong acid will have reacted with the weak base to form a salt (NH₄Cl in this case) and water. **Hint:** Remember that at the equivalence point, the moles of acid equal the moles of base. ### Step 2: Identify the Products The reaction between HCl (strong acid) and NH₃ (weak base) produces NH₄⁺ (ammonium ion) and Cl⁻ (chloride ion). The ammonium ion is the conjugate acid of the weak base. **Hint:** Identify the conjugate acid and base in the reaction. ### Step 3: Analyze the pH At the equivalence point, the solution contains NH₄⁺ ions. Since NH₄⁺ is a weak acid, it will partially ionize in water to produce H⁺ ions (or hydronium ions, H₃O⁺): \[ \text{NH}_4^+ + \text{H}_2\text{O} \rightleftharpoons \text{NH}_3 + \text{H}_3\text{O}^+ \] This reaction increases the concentration of H₃O⁺ ions in the solution, leading to a decrease in pH. **Hint:** Consider how the conjugate acid behaves in water. ### Step 4: Conclusion on pH Since the solution now contains an excess of H₃O⁺ ions due to the ionization of NH₄⁺, the pH will be less than 7, indicating that the solution is acidic. **Hint:** Recall that a pH less than 7 indicates an acidic solution. ### Final Answer At the equivalence point of titrating a strong acid with a weak base, the pH will be less than 7.

To determine the pH at the equivalence point when a strong acid is titrated with a weak base, we can follow these steps: ### Step 1: Understand the Reaction In this titration, we are mixing a strong acid (like HCl) with a weak base (like NH₃). At the equivalence point, all the strong acid will have reacted with the weak base to form a salt (NH₄Cl in this case) and water. **Hint:** Remember that at the equivalence point, the moles of acid equal the moles of base. ### Step 2: Identify the Products ...
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