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The pK(a) of a weak acid, HA, is 4.80. T...

The `pK_(a)` of a weak acid, `HA`, is `4.80`. The `pK_(b)` of a weak base, `BOH`, is `4.78`. The `pH` of an aqueous solution of the corresponding salt, `BA`, will be:

A

8.58

B

4.79

C

7.01

D

9.22

Text Solution

Verified by Experts

The correct Answer is:
C

In aqueous solution, BA(salt) hydrolyses to give
`BA + H_(2)O to underset("base")(BOH) + underset("acid")(HA)`
Now pH since by
`pH=1/2 pK_(w) + ½ pK_(a) -1/2 pK_(b)`
Substituting the given values, we get =`pH=1/2(1.4+4.80-4.78)= 7.01`
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