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Which pair(s) of liquids on mixing is/ar...

Which pair(s) of liquids on mixing is/are expected to show no net volume change and no heat effect?

A

acetone and ethanol

B

chlorobenzene and bromobenzene

C

chloroform and benzene

D

n-butyl chloride and n-butyl bromide

Text Solution

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`DeltaV_("mixing")=0,DeltaH_("mixing")=0implies` Look for ideal solutions.
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Assertion : The difference between DeltaH and DeltaU is not significant for systems consisting of only solids and/or liquids. Reason : Solids and liquids do not suffer any significant volume changes upon heating.