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25mL of 2N HCl, 50 mL "of" 4N HNO(3) and...

25mL of `2N HCl, 50 mL "of" 4N HNO_(3) and xmL H_(2)SO_(4)` are mixed together and the total volume is made up to 1L after dilution. 50mL if this acid ixture completely reacteed with 25mL of a `1 N Na_(2)CO_(3)` solution. The value of x is:

A

250 ml

B

62.5 ml

C

100 ml

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
B
m,eq. of acid's in 50 ml =m. eq. of `Na_(2)CO_(3)`
`25xx2+50 xx 4 +2 xx2 xx X = (1000)/(50) xx 25 xx1`
`x= 62.5 ml`
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