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A binary solid(A^(+) B^(-)) has a zinc b...

A binary solid`(A^(+) B^(-))` has a zinc blende stracture with B ions constituting the lattice and `A^(+)` inos occupying `25%` of the terahedral holes. The formula of the solid is

A

` AB`

B

`A_(2)B`

C

`AB_(2)`

D

`AB_(4)`

Text Solution

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The correct Answer is:
C

Suppose no . Of `B^(-)` ions =N `:.` no. of tetrahedral holes =2N
As `25%` tetrahedral holes are occupied by `A^(+)` ions.
`:." no. of" A^(+) "inos" =(2N)/(4) =(N)/(2)`
`:."Ratio of " A^(+) : B^(-) =N/2: N rArr 1:2`
`:.` the formula is `AB_(2)`
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