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Given E("Cr(2)O(7)^(2-)//Cr^(3+))^(@)=1....

Given `E_("Cr_(2)O_(7)^(2-)//Cr^(3+))^(@)=1.33V,E_(MnO_(4)^(-)//Mn^(2+))^(@)=1.51V`
Among the following, the strongest reducing agent is `E_(Cr^(3+)//Cr)^(@)=-0.74V^(x),E_(MnO_(4)^(-)//Mn^(2+))^(@)=1.51V`
`E_(Cr_(2)O_(7)^(2-)//Cr^(3+))^(@)=1.33V,E_(Cl//Cl^(-))^(@)=1.36V`
Based on the data given above strongest oxidising agent will be

A

`Cl^(-)`

B

`Mn^(2+)`

C

`MnO_(4)^(-)`

D

`Cr^(3+)`

Text Solution

Verified by Experts

Higher the positive value of standard reduction potential of metal ion higher will be its oxidising capacity.
Since `E_(MnO_(4)^(-))^(@)` has value equal to 1.51V hence it is the strongest oxidsiing agent.
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Given E_(cr^(3+)//Cr)^(0)=-0.74 V, E_(MnO_(4)//Mn^(2+))^(0)=1.51 cm E_(Cr_(2)O_(7)^(2-)//Cr^(3+))^(0)=1.33 V, E_(Cl//Cl^(-))^(0)=1.36 V Based on the data given above, strongest oxidising agent will be:

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NCERT EXEMPLAR-ELECTROCHEMISTRY-Electrochemistry
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