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pH of Mixture of acid base...

pH of Mixture of acid base

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The pH of basic buffer mixtures is given by : pH=pK_(a)+log((["Base"])/(["Salt"])) , whereas pH of acidic buffer mixtures is given by: pH= pK_(a)+log((["Salt"])/(["Acid"])) . Addition of little acid or base although shows no appreciable change for all practical purpose, but since the ratio (["Base"])/(["Salt"]) or (["Salt"])/(["Acid"]) change, a slight decrease or increase in pH results in. Mole of HCI required to prepare a buffer solution of pH=8.5 with 0.1 mole of NaCN in one litre solution is: (pK_(a) for CN^(-)=4.61)

The pH of basic buffer mixtures is given by : pH=pK_(a)+log((["Base"])/(["Salt"])) , whereas pH of acidic buffer mixtures is given by: pH= pK_(a)+log((["Salt"])/(["Acid"])) . Addition of little acid or base although shows no appreciable change for all practical purpose, but since the ratio (["Base"])/(["Salt"]) or (["Salt"])/(["Acid"]) change, a slight decrease or increase in pH results in. A weak acid HA after treatment with 12 mL of 0.1M strong base BOH has a pH=5 . At end point, the volume of same base required is 26.6mL K_(a) of acid is:

The Ph of basic buffer mixtures is given by : Ph=Pk_(a)+ log (["Base"])/(["Salt"]) whereas Ph of acidic buffer mixtures is given by : Ph = pK_(a)+"log"(["Salt"])/(["Acid"]) . Addition of little acid or base although shows no appreciable change in Ph for all practical purposes, but sicne the ratio (["Base"])/(["Salt"]) or (["Salt"])/(["Acid"]) changes, a slight decrease or increase in pH results. The volume of 0.2 m NaOH needed to prepare a buffer of pH 4.74 with 50 mL of 0.2 m acetic acid pH_(b) of CH_(3)COO^(-)=9.26 is :