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Halogenation|nitration|vanderwall forces...

Halogenation|nitration|vanderwall forces|atternation effect|ease of halogenation| relative rates of abstraction|monochloronitated product

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Partial hydrogenation|hydration of alcholos| geometric isomerism|ease of dehydro-halogenation

On halogenation, an alkane gives only one monohalogenated product. The alkane may be:

On halogenation, an alkane gives only one monohalogenated product. The alkane may be:

Halogenation is a substitution reaction, where halogen replaces one or more hydrogens of hydrocarbon Chlorine free radical make 1^(@), 2^(@), 3^(@) radicals with almost equal ease, whereas bromine free radicals have a clear preference for the formation of tertiary free radicals. So, bromine is less reactive, and more selectrive whereas chlorine is less selective and more reactive. The relative rate of abstraction of hydrogen by Br^(**) is underset(1600)(3^(@)) gt underset(82)(2^(@)) gt underset(1)(1^(@)) underset(5)(3^(@)) gt underset(3.8)(2^(@)) gt underset(1)(1^(@)) 1-halo-2,3-dimethyl butane will be obtained in better yields, if halogen is:

Halogenation is a substitution reaction, where halogen replaces one or more hydrogens of hydrocarbon Chlorine free radical make 1^(@), 2^(@), 3^(@) radicals with almost equal ease, whereas bromine free radicals have a clear preference for the formation of tertiary free radicals. So, bromine is less reactive, and more selectrive whereas chlorine is less selective and more reactive. The relative rate of abstraction of hydrogen by Br^(**) is underset(1600)(3^(@)) gt underset(82)(2^(@)) gt underset(1)(1^(@)) underset(5)(3^(@)) gt underset(3.8)(2^(@)) gt underset(1)(1^(@)) Above product will obtained in better yield if X is

Halogenation is a substitution reaction, where halogen replaces one or more hydrogens of hydrocarbon Chlorine free radical make 1^(@), 2^(@), 3^(@) radicals with almost equal ease, whereas bromine free radicals have a clear preference for the formation of tertiary free radicals. So, bromine is less reactive, and more selectrive whereas chlorine is less selective and more reactive. The relative rate of abstraction of hydrogen by Br^(**) is underset(1600)(3^(@)) gt underset(82)(2^(@)) gt underset(1)(1^(@)) underset(5)(3^(@)) gt underset(3.8)(2^(@)) gt underset(1)(1^(@)) What is the value of x (% yield of product)?

Halogenation is a substitution reaction, where halogen replaces one or more hydrogens of hydrocarbon Chlorine free radical make 1^(@), 2^(@), 3^(@) radicals with almost equal ease, whereas bromine free radicals have a clear preference for the formation of tertiary free radicals. So, bromine is less reactive, and more selectrive whereas chlorine is less selective and more reactive. The relative rate of abstraction of hydrogen by Br^(**) is underset(1600)(3^(@)) gt underset(82)(2^(@)) gt underset(1)(1^(@)) underset(5)(3^(@)) gt underset(3.8)(2^(@)) gt underset(1)(1^(@)) CH_(3)-overset(CH_(3))overset(|)(CH)-CH_(3)overset(Cl_(2)//hv)(to) product Major product in the above reactio is: