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Maximum number of moles of electrons tak...

Maximum number of moles of electrons taken up by one mole of `NO_(3)^(-)` when it is reduced to :

A

`NH_3`

B

`NH_2OH`

C

`NO`

D

`NO_2`

Text Solution

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The correct Answer is:
To determine the maximum number of moles of electrons taken up by one mole of \( \text{NO}_3^- \) when it is reduced, we need to analyze the oxidation states of nitrogen in various possible reduction products. ### Step-by-Step Solution: 1. **Identify the oxidation state of nitrogen in \( \text{NO}_3^- \)**: - Let the oxidation state of nitrogen be \( x \). - The oxidation states of oxygen is \(-2\). - The equation based on the charge of the ion is: \[ x + 3(-2) = -1 \] - Simplifying this gives: \[ x - 6 = -1 \implies x = +5 \] - Thus, the oxidation state of nitrogen in \( \text{NO}_3^- \) is +5. 2. **Consider possible reduction products**: - We will consider the following compounds as potential reduction products: - \( \text{NH}_3 \) (Ammonia) - \( \text{NH}_2\text{OH} \) (Hydroxylamine) - \( \text{NO} \) (Nitric oxide) - \( \text{NO}_2 \) (Nitrogen dioxide) 3. **Calculate the oxidation state of nitrogen in each product**: - **For \( \text{NH}_3 \)**: \[ x + 3(+1) = 0 \implies x = -3 \] - **For \( \text{NH}_2\text{OH} \)**: \[ x + 2(+1) + (-2) = 0 \implies x = -1 \] - **For \( \text{NO} \)**: \[ x + 1(-2) = 0 \implies x = +2 \] - **For \( \text{NO}_2 \)**: \[ x + 2(-2) = 0 \implies x = +4 \] 4. **Calculate the change in oxidation state (Δ) for each product**: - **For \( \text{NH}_3 \)**: \[ \Delta = 5 - (-3) = 8 \] - **For \( \text{NH}_2\text{OH} \)**: \[ \Delta = 5 - (-1) = 6 \] - **For \( \text{NO} \)**: \[ \Delta = 5 - 2 = 3 \] - **For \( \text{NO}_2 \)**: \[ \Delta = 5 - 4 = 1 \] 5. **Determine the maximum number of moles of electrons**: - The maximum change in oxidation state occurs when \( \text{NO}_3^- \) is reduced to \( \text{NH}_3 \), which corresponds to a change of 8. - Therefore, the maximum number of moles of electrons taken up by one mole of \( \text{NO}_3^- \) is **8 moles**. ### Final Answer: The maximum number of moles of electrons taken up by one mole of \( \text{NO}_3^- \) when it is reduced to \( \text{NH}_3 \) is **8 moles**.

To determine the maximum number of moles of electrons taken up by one mole of \( \text{NO}_3^- \) when it is reduced, we need to analyze the oxidation states of nitrogen in various possible reduction products. ### Step-by-Step Solution: 1. **Identify the oxidation state of nitrogen in \( \text{NO}_3^- \)**: - Let the oxidation state of nitrogen be \( x \). - The oxidation states of oxygen is \(-2\). - The equation based on the charge of the ion is: ...
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