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Which of the following statements is/are...

Which of the following statements is/are true if 1 mol of `H_(3)PO_(x)` is completely neutralized by 40g of NaOH?

A

x = 2 and acid is monobasic

B

x = 3 and acid is dibasic

C

x = 4 and acid is tribasic

D

x = 2 and acid does not form acid salt

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the information given and determine the validity of the statements regarding the neutralization of 1 mole of \( H_3PO_x \) by 40g of NaOH. ### Step-by-Step Solution: 1. **Calculate Moles of NaOH:** - The molar mass of NaOH is 40 g/mol. - Given that we have 40 g of NaOH: \[ \text{Moles of NaOH} = \frac{40 \, \text{g}}{40 \, \text{g/mol}} = 1 \, \text{mol} \] **Hint:** Remember that the number of moles can be calculated using the formula: \[ \text{Moles} = \frac{\text{Mass}}{\text{Molar Mass}} \] 2. **Neutralization Reaction:** - The neutralization reaction can be represented as: \[ H_3PO_x + NaOH \rightarrow \text{Products} \] - For neutralization, the equivalents of acid must equal the equivalents of base. 3. **Determine the Valency Factor (n):** - The valency factor (n) for NaOH is 1 because it can donate one hydroxide ion (OH⁻). - Since 1 mole of NaOH neutralizes 1 mole of \( H_3PO_x \), the valency factor for \( H_3PO_x \) must also be 1. 4. **Identify the Possible Forms of \( H_3PO_x \):** - The formula \( H_3PO_x \) indicates that it is a phosphoric acid derivative. - The possible values for \( x \) can be 2, 3, or 4: - \( H_3PO_2 \) (phosphorous acid) - can release 1 H⁺ - \( H_3PO_3 \) (phosphoric acid) - can release 2 H⁺ - \( H_3PO_4 \) (phosphoric acid) - can release 3 H⁺ - Since \( H_3PO_x \) is neutralized by 1 mole of NaOH, it can only release 1 H⁺ ion, indicating \( x = 2 \). 5. **Conclusion on Acid Type:** - Since \( H_3PO_x \) can only release one H⁺ ion, it is monobasic. - Therefore, \( H_3PO_2 \) is the only valid form for \( H_3PO_x \) in this context. 6. **Determine the Nature of the Salt Formed:** - When \( H_3PO_2 \) reacts with NaOH, it forms an acidic salt \( NaH_2PO_2 \) and water. - Since it can only release 1 H⁺, it cannot form a normal salt. ### Final Statements: Based on the analysis: - The true statements regarding \( H_3PO_x \) are: 1. It is monobasic (can release only 1 H⁺). 2. It can form an acidic salt when reacting with NaOH.

To solve the question, we need to analyze the information given and determine the validity of the statements regarding the neutralization of 1 mole of \( H_3PO_x \) by 40g of NaOH. ### Step-by-Step Solution: 1. **Calculate Moles of NaOH:** - The molar mass of NaOH is 40 g/mol. - Given that we have 40 g of NaOH: \[ ...
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