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10 g of oxalate was dissolved in 300 mL ...

10 g of oxalate was dissolved in 300 mL of solution. This solution required 250 mL of `(M/10)KMnO_(4)`in acidic medium for complete oxidation. The percentage purity of oxalate ion in the salt is :

A

0.55

B

0.578

C

0.45

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
A

Number of equivalents of oxalate = Number of equivalents of `KMnO_(4)=(250)/(1000)xx(5)/(10)=(1)/(8)`
implies `(1)/(8)=(g)/(88)/(2)implies g=5.5gram` therefore %purity=`(5.5)/(10)xx100=55%`
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