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In the reaction A + B rarr Products, kee...

In the reaction `A + B rarr` Products, keeping [A] constant if [B] is doubled , the rate becomes double and keeping [B] constant if [A] is doubled , the rate becomes four times. The order of reaction is :

A

1

B

2

C

3

D

4

Text Solution

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The correct Answer is:
To determine the order of the reaction given the information in the question, we can follow these steps: ### Step 1: Write the rate law expression The rate of the reaction can be expressed as: \[ \text{Rate} = k[A]^m[B]^n \] where: - \( k \) is the rate constant, - \( [A] \) is the concentration of reactant A, - \( [B] \) is the concentration of reactant B, - \( m \) is the order with respect to A, - \( n \) is the order with respect to B. ### Step 2: Analyze the first condition Keeping \([A]\) constant and doubling \([B]\): - Initial rate: \( r_1 = k[A]^m[B]^n \) - New rate when \([B]\) is doubled: \[ r_2 = k[A]^m[2B]^n = k[A]^m \cdot 2^n[B]^n = 2^n \cdot r_1 \] According to the problem, \( r_2 = 2r_1 \). Therefore: \[ 2^n \cdot r_1 = 2r_1 \] Dividing both sides by \( r_1 \) (assuming \( r_1 \neq 0 \)): \[ 2^n = 2 \] This implies: \[ n = 1 \] ### Step 3: Analyze the second condition Keeping \([B]\) constant and doubling \([A]\): - New rate when \([A]\) is doubled: \[ r_3 = k[2A]^m[B]^n = k \cdot 2^m[A]^m[B]^n = 2^m \cdot r_1 \] According to the problem, \( r_3 = 4r_1 \). Therefore: \[ 2^m \cdot r_1 = 4r_1 \] Dividing both sides by \( r_1 \): \[ 2^m = 4 \] This implies: \[ 2^m = 2^2 \] Thus: \[ m = 2 \] ### Step 4: Determine the overall order of the reaction The overall order of the reaction is the sum of the individual orders: \[ \text{Overall order} = m + n = 2 + 1 = 3 \] ### Conclusion The order of the reaction is **3**.

To determine the order of the reaction given the information in the question, we can follow these steps: ### Step 1: Write the rate law expression The rate of the reaction can be expressed as: \[ \text{Rate} = k[A]^m[B]^n \] where: - \( k \) is the rate constant, - \( [A] \) is the concentration of reactant A, ...
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