Home
Class 12
CHEMISTRY
The rate of chemical reaction : (Non-zer...

The rate of chemical reaction : (Non-zero order)

A

Increases as the reaction proceeds

B

Decreases as the reaction proceeds

C

May increase or decrease during reaction

D

Remains constant as the reaction proceeds

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the behavior of the rate of a non-zero order chemical reaction, we will analyze the rate equation and how it changes as the concentration of the reactant changes over time. ### Step-by-Step Solution: 1. **Understanding the Rate Equation**: The rate of a chemical reaction can be expressed as: \[ R = k[A]^n \] where: - \( R \) is the rate of the reaction, - \( k \) is the rate constant, - \( [A] \) is the concentration of the reactant, - \( n \) is the order of the reaction. 2. **Identifying Non-Zero Order**: For a non-zero order reaction, \( n \) can be either positive or negative: - If \( n > 0 \): The rate depends on the concentration of \( A \). - If \( n < 0 \): The rate will still depend on the concentration of \( A \), but in a different manner. 3. **Case 1: Positive Order Reaction (n > 0)**: - As the reaction proceeds, the concentration of \( A \) decreases because it is being consumed. - Since \( n \) is positive, the rate \( R \) will decrease as \( [A] \) decreases. - Therefore, for a positive order reaction, the rate **decreases** over time. 4. **Case 2: Negative Order Reaction (n < 0)**: - In this case, as the concentration of \( A \) decreases, the rate equation can be rewritten as: \[ R = k[A]^{-n} = \frac{k}{[A]^{|n|}} \] - Here, \( |n| \) is a positive number since \( n \) is negative. - As \( [A] \) decreases, the denominator decreases, leading to an **increase** in the rate \( R \). 5. **Conclusion**: - For a non-zero order reaction: - If \( n > 0 \), the rate decreases. - If \( n < 0 \), the rate increases. - Therefore, the rate of a non-zero order reaction can either **increase or decrease** depending on whether the order is positive or negative. ### Final Answer: The correct option is that the rate of a non-zero order reaction may **increase or decrease** during the reaction.

To solve the question regarding the behavior of the rate of a non-zero order chemical reaction, we will analyze the rate equation and how it changes as the concentration of the reactant changes over time. ### Step-by-Step Solution: 1. **Understanding the Rate Equation**: The rate of a chemical reaction can be expressed as: \[ R = k[A]^n ...
Promotional Banner

Similar Questions

Explore conceptually related problems

Assertion. Rate constant of a zero order reaction has the same units as those of the rate of reaction. Reason. For a zero order reaction, Rate = Rate constant.

A : The rate constant of zero order reaction is equal to rate of reaction. R : t_(1//2) for zero order reaction is directly proportional to initial concentration.

Half life in a first order and zero order reaction are same then ratio of initial rates in Ist and zero order is : (Given initial concentration is same)

A : At equilibrium concentration of the reactant and product does not change with time for a chemical reaction. R : The rate of reaction is zero at equilibrium

The rate constant for a chemical reaction has unit litre mol^(-1) sec^(-1) . Find the order of the reaction.

Half life of a first order reaction and a zero order reaction are same. Then the ratio of the initial rate of the first order reaction to that of zero order reaction is