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For the following elementary homogeneous...

For the following elementary homogeneous reaction, the unit of rate constant is : `A+B overset(k) rarr C`

A

`"mol"^(-1) L s^(-1)`

B

`s^(-1)`

C

s

D

`"mol L"^(-1) s^(-1)`

Text Solution

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The correct Answer is:
To determine the unit of the rate constant (k) for the elementary homogeneous reaction \( A + B \overset{k}{\rightarrow} C \), we can follow these steps: ### Step 1: Identify the Reaction Order For the given elementary reaction, the stoichiometric coefficients of the reactants \( A \) and \( B \) are both 1. Therefore, the overall order of the reaction is the sum of the stoichiometric coefficients: \[ \text{Order} = 1 + 1 = 2 \] ### Step 2: Write the Rate Law For an elementary reaction, the rate law can be expressed as: \[ \text{Rate} = k[A]^1[B]^1 = k[A][B] \] ### Step 3: Determine the Units of Rate The rate of a reaction is typically expressed in terms of concentration change over time. The unit of rate is: \[ \text{Unit of Rate} = \text{mole L}^{-1} \text{s}^{-1} \] ### Step 4: Relate the Units of Rate Constant to the Reaction Order The unit of the rate constant \( k \) can be derived from the rate law. Rearranging the rate equation gives: \[ k = \frac{\text{Rate}}{[A][B]} \] ### Step 5: Substitute the Units Substituting the units into the equation: \[ \text{Unit of } k = \frac{\text{mole L}^{-1} \text{s}^{-1}}{(\text{mole L}^{-1})(\text{mole L}^{-1})} \] This simplifies to: \[ \text{Unit of } k = \frac{\text{mole L}^{-1} \text{s}^{-1}}{\text{mole}^2 \text{L}^{-2}} = \text{mole}^{-1} \text{L} \text{s}^{-1} \] ### Conclusion Thus, the unit of the rate constant \( k \) for the reaction \( A + B \rightarrow C \) is: \[ \text{Unit of } k = \text{mole}^{-1} \text{L} \text{s}^{-1} \] ### Final Answer The correct option is \( \text{mole}^{-1} \text{L} \text{s}^{-1} \). ---

To determine the unit of the rate constant (k) for the elementary homogeneous reaction \( A + B \overset{k}{\rightarrow} C \), we can follow these steps: ### Step 1: Identify the Reaction Order For the given elementary reaction, the stoichiometric coefficients of the reactants \( A \) and \( B \) are both 1. Therefore, the overall order of the reaction is the sum of the stoichiometric coefficients: \[ \text{Order} = 1 + 1 = 2 \] ...
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