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What are fuel cells ? Explain the electr...

What are fuel cells ? Explain the electrode reactions involved in the working of `H_(2) - O_(2)` fuel cell.

Text Solution

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Those galvanic cells which give us direct electrical energy by the combustion of fuels like hydrogen, methane, methanol etc. are called fuel cell. The reactions taking place in hydrogen – oxygen fuel cell:
At cathode : `O_(2(g) + 2H_(2)O _(1) + 4e^(-)to 4OH_(aq)^(-)`
`underline(At anode : 2H_(2(g)+ 4OH^_(aq)^(-)rightarrow 4H_(2)O_((1))+ 4e`
Net reaction : `2H_(2)(g) + O_(2)(g) rightarrow 2H_(2) O _(1)`
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Knowledge Check

  • EMF of an H_(2)-O_(2) fuel cell

    A
    Is indepenent of partial pressures of `H_(2)` and `O_(2)`
    B
    Decreases on increasing `P_(H_(2))` and `P_(O_(2))`
    C
    Increases on increasing `P_(H_(2))` and `P_(O_(2))`
    D
    Varies with the concentration of `OH^(-)` ions in the cathodic and anodic compartments.
  • A fuel cell is

    A
    the voltaic cells in which discontinuous supply of fuels are send at anode to give oxidation
    B
    the voltaic cell in which fuels such as : `CH_(4) , H_(2) , CO` are used up at anode
    C
    it involves the reactions of `H_(2) - O_(2)` fuel cell such as
    Cathode : `2 H_(2) + 4OH^(-) to 4 H_(2) O(l) + 4e`
    Anode : `O_(2) + 2 H_(2)O (l) + 4e to 4 OH^(-)`
    D
    the efficiency of a `H_(2) - O_(2)` fuel cell is very low
  • The electrode reactions that takes place at the anode of CH_(4)-O_(2) fuel cell is :

    A
    `2O_(2)+8H^(+)+8e^(-) rarr 4H_(2)O`
    B
    `CH_(4)+2H_(2)O rarr CO_(2)+8H^(+)+8e^(-)`
    C
    `CH_(4)+2O_(2) rarr O_(2)+2H_(2)O`
    D
    `2H^(+)+2e^(-) rarr H_(2)`
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