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In acidic medium is converted to Mn2+....

In acidic medium is converted to Mn2+. The quantity of electricity in faraday required to reduce `0.5` mole `MnO_(4)^(-)` to `Mn^(2+)` would be :

A

`2.5`

B

5

C

1

D

0.5

Text Solution

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The correct Answer is:
To solve the problem of determining the quantity of electricity in Faraday required to reduce 0.5 moles of MnO4^- to Mn^2+ in acidic medium, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: The reduction of permanganate ion (MnO4^-) to manganese ion (Mn^2+) in acidic medium can be represented as: \[ \text{MnO}_4^- + \text{8H}^+ + \text{5e}^- \rightarrow \text{Mn}^{2+} + \text{4H}_2\text{O} \] This equation shows that 1 mole of MnO4^- is reduced to 1 mole of Mn^2+ and involves the transfer of 5 electrons. 2. **Calculate the Moles of Electrons for 0.5 Moles**: Since the reaction shows that 1 mole of MnO4^- requires 5 moles of electrons, for 0.5 moles of MnO4^-, the number of moles of electrons required can be calculated as: \[ \text{Moles of electrons} = 0.5 \text{ moles MnO}_4^- \times 5 \text{ moles e}^- = 2.5 \text{ moles e}^- \] 3. **Convert Moles of Electrons to Faraday**: One mole of electrons corresponds to one Faraday (approximately 96500 coulombs). Therefore, the quantity of electricity in Faraday required for 2.5 moles of electrons is: \[ \text{Faraday required} = 2.5 \text{ moles e}^- \times 1 \text{ Faraday/mole e}^- = 2.5 \text{ Faraday} \] 4. **Conclusion**: The quantity of electricity required to reduce 0.5 moles of MnO4^- to Mn^2+ in acidic medium is **2.5 Faraday**. ### Final Answer: The quantity of electricity required is **2.5 Faraday**. ---

To solve the problem of determining the quantity of electricity in Faraday required to reduce 0.5 moles of MnO4^- to Mn^2+ in acidic medium, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: The reduction of permanganate ion (MnO4^-) to manganese ion (Mn^2+) in acidic medium can be represented as: \[ \text{MnO}_4^- + \text{8H}^+ + \text{5e}^- \rightarrow \text{Mn}^{2+} + \text{4H}_2\text{O} ...
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