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During the electrolysis of molten NaCl s...

During the electrolysis of molten NaCl solution, 230 g of sodium metal is deposited on the cathode, then how many moles of chlorine will be obtained at anode?

A

`10.0`

B

`5.0`

C

`35.5`

D

`17.0`

Text Solution

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The correct Answer is:
To solve the problem of how many moles of chlorine will be obtained at the anode during the electrolysis of molten NaCl when 230 g of sodium metal is deposited on the cathode, we can follow these steps: ### Step 1: Determine the number of moles of sodium deposited To find the number of moles of sodium (Na) deposited, we can use the formula: \[ \text{Number of moles} = \frac{\text{mass (g)}}{\text{molar mass (g/mol)}} \] The molar mass of sodium (Na) is approximately 23 g/mol. Given that 230 g of sodium is deposited: \[ \text{Number of moles of Na} = \frac{230 \, \text{g}}{23 \, \text{g/mol}} = 10 \, \text{moles} \] ### Step 2: Relate moles of sodium to moles of chlorine During the electrolysis of NaCl, the following reactions occur: - At the cathode (reduction): \[ \text{Na}^+ + e^- \rightarrow \text{Na} \] - At the anode (oxidation): \[ 2\text{Cl}^- \rightarrow \text{Cl}_2 + 2e^- \] From the cathode reaction, we see that 1 mole of Na is produced for every 1 mole of electrons (1 Farad). From the anode reaction, we see that 1 mole of Cl2 is produced for every 2 moles of electrons. ### Step 3: Calculate the moles of chlorine produced Since 10 moles of sodium were deposited, this means that 10 moles of electrons were used (as 1 mole of Na corresponds to 1 mole of electrons). Now, to find out how many moles of Cl2 are produced from the 10 moles of electrons: \[ \text{Moles of Cl}_2 = \frac{\text{Moles of electrons}}{2} = \frac{10}{2} = 5 \, \text{moles} \] ### Conclusion Therefore, the number of moles of chlorine gas (Cl2) produced at the anode is **5 moles**. ---

To solve the problem of how many moles of chlorine will be obtained at the anode during the electrolysis of molten NaCl when 230 g of sodium metal is deposited on the cathode, we can follow these steps: ### Step 1: Determine the number of moles of sodium deposited To find the number of moles of sodium (Na) deposited, we can use the formula: \[ \text{Number of moles} = \frac{\text{mass (g)}}{\text{molar mass (g/mol)}} \] ...
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