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Give the products available on the catho...

Give the products available on the cathode and the anode respectively during the electrolysis of an aqueous solution of `MgSO_(4)` between inert electrodes.

A

`H_(2)(g) and O_2(g)`

B

`O_(2) (g) and H_(2) (g)`

C

`O_(2)(g) andMg (s)`

D

`O_(2)(g) and SO_(2) (g)`

Text Solution

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The correct Answer is:
To determine the products formed at the cathode and anode during the electrolysis of an aqueous solution of magnesium sulfate (MgSO₄) using inert electrodes, we can follow these steps: ### Step 1: Identify the Electrolysis Setup In electrolysis, we have two electrodes: the anode (positive electrode) and the cathode (negative electrode). An aqueous solution of MgSO₄ contains Mg²⁺ ions and SO₄²⁻ ions, along with water (H₂O). ### Step 2: Determine the Reactions at the Anode At the anode, oxidation occurs. We need to consider the possible species that can be oxidized: - The sulfate ion (SO₄²⁻) does not undergo oxidation under these conditions. - Water (H₂O) can be oxidized to produce oxygen gas (O₂). The half-reaction for the oxidation of water is: \[ 2 H₂O \rightarrow O₂ + 4 H⁺ + 4 e⁻ \] Thus, the product at the anode is oxygen gas (O₂). ### Step 3: Determine the Reactions at the Cathode At the cathode, reduction occurs. We need to consider the possible species that can be reduced: - Magnesium ions (Mg²⁺) can be reduced to magnesium metal (Mg). - Water (H₂O) can also be reduced to produce hydrogen gas (H₂). The reduction half-reaction for magnesium is: \[ Mg^{2+} + 2 e⁻ \rightarrow Mg \] The reduction half-reaction for water is: \[ 2 H₂O + 2 e⁻ \rightarrow H₂ + 2 OH⁻ \] To determine which reaction occurs, we compare the standard reduction potentials: - The standard reduction potential for Mg²⁺ is -2.37 V. - The standard reduction potential for water is -0.42 V. Since the reduction potential for water is higher (less negative), water will be reduced instead of magnesium ions. Thus, the product at the cathode is hydrogen gas (H₂). ### Conclusion The products formed during the electrolysis of an aqueous solution of MgSO₄ are: - At the anode: Oxygen gas (O₂) - At the cathode: Hydrogen gas (H₂) ### Final Answer - Products at the anode: O₂ - Products at the cathode: H₂

To determine the products formed at the cathode and anode during the electrolysis of an aqueous solution of magnesium sulfate (MgSO₄) using inert electrodes, we can follow these steps: ### Step 1: Identify the Electrolysis Setup In electrolysis, we have two electrodes: the anode (positive electrode) and the cathode (negative electrode). An aqueous solution of MgSO₄ contains Mg²⁺ ions and SO₄²⁻ ions, along with water (H₂O). ### Step 2: Determine the Reactions at the Anode At the anode, oxidation occurs. We need to consider the possible species that can be oxidized: - The sulfate ion (SO₄²⁻) does not undergo oxidation under these conditions. ...
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