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In Hall process, in the production of A1...

In Hall process, in the production of A1, caebon is used as the anode material . The reaction are :

A

Anode : `A1^(3+) + 3e^(-)rightaorrow A1`
cathod:
`C(s)+ 20^(2-) rightarrow CO_(2) (g)+ 4e^(-)`

B

Anode: `C_(s)+O_(2)rightarrow CO_(2)`
Cathod : `A1^(3+) + 3e^(-)rightarrowA1`

C

Anode : `A1rightarrow A1^(3+)+e^(-)`
Cathod : `Co_(2)+4e^(-)rightarrow C(s) + 2o^2-)`

D

None of above

Text Solution

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To solve the question regarding the Hall process in the production of aluminum, we will outline the key reactions that take place during the electrolysis of aluminum oxide (Al₂O₃) using carbon as the anode material. ### Step-by-Step Solution: 1. **Understanding the Setup**: - The Hall process involves the electrolysis of aluminum oxide (Al₂O₃) dissolved in a molten electrolyte, typically a mixture of cryolite (Na₃AlF₆) and aluminum fluoride (AlF₃). - Carbon electrodes are used, where the anode is made of carbon and the cathode is typically a carbon lining of the cell. 2. **Electrolyte Preparation**: - The aluminum oxide (Al₂O₃) is mixed with the electrolyte (cryolite and aluminum fluoride) to lower its melting point and increase conductivity. 3. **Electrolysis Reaction**: - When electricity is passed through the molten electrolyte, aluminum ions (Al³⁺) migrate to the cathode, and oxide ions (O²⁻) migrate to the anode. - The reactions at the electrodes can be summarized as follows: **At the Cathode (Reduction)**: \[ \text{Al}^{3+} + 3e^- \rightarrow \text{Al} (l) \] - Aluminum ions gain electrons (reduction) to form liquid aluminum. **At the Anode (Oxidation)**: \[ 2\text{O}^{2-} \rightarrow \text{O}_2 (g) + 4e^- \] - Oxide ions lose electrons (oxidation) to form oxygen gas. 4. **Reaction of Oxygen with Carbon**: - The oxygen produced at the anode reacts with the carbon anode to form carbon monoxide (CO) or carbon dioxide (CO₂): \[ \text{C} + \text{O}_2 \rightarrow \text{CO}_2 (g) \] or \[ 2\text{C} + \text{O}_2 \rightarrow 2\text{CO} (g) \] 5. **Overall Reaction**: - The overall reaction for the Hall process can be summarized as: \[ 2\text{Al}_2\text{O}_3 (l) \rightarrow 4\text{Al} (l) + 3\text{O}_2 (g) \] - This indicates that aluminum is produced while oxygen is released as a byproduct. ### Summary of Reactions: - **At Cathode**: \[ \text{Al}^{3+} + 3e^- \rightarrow \text{Al} (l) \] - **At Anode**: \[ 2\text{O}^{2-} \rightarrow \text{O}_2 (g) + 4e^- \] - **Carbon Reaction**: \[ \text{C} + \text{O}_2 \rightarrow \text{CO}_2 (g) \] or \[ 2\text{C} + \text{O}_2 \rightarrow 2\text{CO} (g) \]

To solve the question regarding the Hall process in the production of aluminum, we will outline the key reactions that take place during the electrolysis of aluminum oxide (Al₂O₃) using carbon as the anode material. ### Step-by-Step Solution: 1. **Understanding the Setup**: - The Hall process involves the electrolysis of aluminum oxide (Al₂O₃) dissolved in a molten electrolyte, typically a mixture of cryolite (Na₃AlF₆) and aluminum fluoride (AlF₃). - Carbon electrodes are used, where the anode is made of carbon and the cathode is typically a carbon lining of the cell. ...
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