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The equivalent conductances of two stron...

The equivalent conductances of two strong electrolytes at infinite dilution in H2O (where ions move freely through a solution) at `25^(@)C`are given below:
`wedge_(CH_(3)COONa^(@) = 91.0Scm^(2)//equ iv` , `wedge_HCl^(@)= 426.25cm^(2)//equiv`
What additional information/quantity one needs to calculate `overset(o)(wedge)` of an aqueous solution of acetic acid?

A

`overset(o)(wedge)` of NaC1

B

`3 overset(o)(wedge)` of `CH_(3)COOK`

C

The limitation equivalent conductance of `H^(+) (wedge_(H^+)^(@))`

D

`overset(o)wedge` of chlorocetic acid `(C1CH_(2)COOH)`

Text Solution

AI Generated Solution

To calculate the equivalent conductance of an aqueous solution of acetic acid (CH₃COOH) at infinite dilution, we need to use the concept of equivalent conductance and the contributions from the ions involved. Here’s a step-by-step solution: ### Step 1: Understand the concept of equivalent conductance Equivalent conductance (Λ) at infinite dilution is the sum of the conductances of the individual ions present in the electrolyte. For a weak electrolyte like acetic acid, we need to consider the ions it dissociates into. ### Step 2: Write the dissociation equation for acetic acid Acetic acid (CH₃COOH) dissociates in water as follows: \[ \text{CH}_3\text{COOH} \rightleftharpoons \text{CH}_3\text{COO}^- + \text{H}^+ \] ...
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