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A solution containing one mole per litre...

A solution containing one mole per litre of each `Cu(NO_(3))_(2), AgNO_(3), Hg_(2)(NO_(3))_(2)` is being electrolysed by using inert electrodes. The values of standard electrode potentials in volts (reduction potentials) are
`Ag^(+)//Ag = +0.80 V, HG_(2)^(2+)//Hg = +0.79 V`
`Cu^(+)//Cu = +0.34 V, Mg^(2+)//Mg = -2.37 V`
With increasing valtage, the sequence of deposition of metals on the cathode will be

A

Ag, Hg, Cu, Mg

B

Mg, Cu, Hg, Ag

C

Ag, Hg, Cu

D

Cu, Hg, Ag

Text Solution

Verified by Experts

The reduction potentials (as given) of the ions are in order :
`Ag^(+)gt Hg_2^(2+)gt Cu^(2+)gtM g^(2+)`
`M g^(2+)(aq)` will not be deposition of the metals will be Ag, Hg, Cu
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