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Electrolysis of dilute aqueous NaCl solu...

Electrolysis of dilute aqueous NaCl solution was carried out by passing 10 mA current. The time required to liberate 0.01 mole of `H_2` gas at the cathode is : `(1f= 96500C mol^(-1)`

A

`9.65 xx10^(4)s`

B

`19.3xx10^(4)S`

C

`28.95xx10^(4)S`

D

`38.6xx10^(4)s`

Text Solution

AI Generated Solution

To solve the problem of determining the time required to liberate 0.01 moles of H₂ gas at the cathode during the electrolysis of dilute aqueous NaCl solution, we can follow these steps: ### Step 1: Determine the charge required to liberate 0.01 moles of H₂ gas. The balanced equation for the electrolysis of water (which occurs in dilute NaCl solution) at the cathode is: \[ 2H_2O + 2e^- \rightarrow H_2 + 2OH^- \] From this equation, we see that 2 moles of electrons (2e⁻) are required to produce 1 mole of H₂ gas. Therefore, to produce 0.01 moles of H₂ gas, we need: \[ \text{Moles of electrons} = 2 \times 0.01 = 0.02 \text{ moles of electrons} \] ...
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