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For a 1^(st) order reaction (gaseous) (c...

For a `1^(st)` order reaction (gaseous) (cont. V, T) `aA rarr (b-1) B+C` (with `b gt a`) the pressure of the system increased by `50((b)/(a)-1)%` in a time of 10 min. The halflife of the reaction is therefore (in min).

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To solve the problem, we need to determine the half-life of a first-order reaction given the increase in pressure over a specified time. Let's break this down step by step. ### Step 1: Understand the Reaction The reaction is given as: \[ aA \rightarrow (b-1)B + C \] where \( b > a \). ### Step 2: Initial and Final Pressure At time \( t = 0 \), the initial pressure of the system is \( P_0 \). After some time \( t \), the pressure increases by \( 50\left(\frac{b}{a} - 1\right)\% \). ### Step 3: Calculate the Increase in Pressure The increase in pressure can be expressed as: \[ \Delta P = P_0 \cdot 0.5\left(\frac{b}{a} - 1\right) \] Thus, the final pressure \( P \) after time \( t \) can be written as: \[ P = P_0 + \Delta P = P_0 + 0.5\left(\frac{b}{a} - 1\right) P_0 = P_0 \left(1 + 0.5\left(\frac{b}{a} - 1\right)\right) \] ### Step 4: Relate the Change in Pressure to the Reaction Progress Let \( x \) be the change in moles of \( A \) that have reacted. The change in pressure due to the reaction can be expressed as: \[ P = P_0 - \frac{x}{a} + \frac{(b-1)x}{a} + \frac{x}{a} = P_0 + \frac{(b-1)x}{a} \] Setting the two expressions for \( P \) equal gives: \[ P_0 + \frac{(b-1)x}{a} = P_0 \left(1 + 0.5\left(\frac{b}{a} - 1\right)\right) \] ### Step 5: Solve for \( x \) From the above equation, we can isolate \( x \): \[ \frac{(b-1)x}{a} = 0.5\left(\frac{b}{a} - 1\right) P_0 \] This simplifies to: \[ x = \frac{0.5\left(\frac{b}{a} - 1\right) a P_0}{b-1} \] ### Step 6: Determine the Half-Life For a first-order reaction, the half-life \( t_{1/2} \) is given by: \[ t_{1/2} = \frac{0.693}{k} \] Where \( k \) is the rate constant. Since we know that the pressure increased by \( 50\left(\frac{b}{a} - 1\right)\% \) in 10 minutes, and this corresponds to a decrease in concentration of \( A \) to half its initial value, we can conclude: \[ t_{1/2} = 10 \text{ minutes} \] ### Final Answer The half-life of the reaction is: \[ \boxed{10 \text{ minutes}} \]
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MOTION-Chemical Kinetics-Exercise - 2 (Level-II) (COMPREHENSION - 2)
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  2. Half-life for the zero order reaction A(g) to B(g)+C(g) and half-life ...

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  3. For the reaction A  B, the rate law expression is -(d[A])/(dt) =k [A...

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  4. For a reaction : 2A + 2B rarr products, the rate law expression is r =...

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  5. Half life for which of the following varies with initial concentration...

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  6. Match the column

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  7. Column-I and Column-II contains four entries each.Entries of Column-I ...

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  8. Consider the following first order decomposition process: Here, '...

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  9. 5A rarr Product In above reaction, half-life period is directly propor...

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  10. The complex [Co(NH(3))(5)F]^(2+) reacts with water according to the eq...

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  11. An optically active compound A upon acid catalysed hydrolysis yield tw...

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  12. The reaction CH(3) – CH(2) – NO(2) + OH^(–) rarr CH(3) – CH – NO(2) + ...

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  13. Decomposition of H(2)O(2) is a first order reaction. A solution of H(...

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  14. The reaction A B, obeys the rate law for pseudo first order kinetics...

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  15. For any acid catalysed reaction, Aoverset(H^(+))rarrB half- life per...

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  16. Statement-1: Temperature coefficient of a one step reaction may be neg...

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  17. Statement-1 : The overall rate of a reversible reaction may decrease w...

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  18. Statement-1: In a reversible endothemic reactiuon, E(act) of forward ...

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  19. Statement-1 : A catalyst provides an alternative path to the reaction ...

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  20. Statement-1 : Rate of a chemical reaction increases as the temperature...

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