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In the given reaction: C(6) H(5) - ove...

In the given reaction:
`C_(6) H_(5) - overset(O)overset(||)(C )-H overset(NH_(2) OH//H^(e ))(rarr)` [x], [x] will be ,

A

Only syn oxime

B

Only anti oxime

C

Mixture of syn and anti oxime

D

Secondary amide

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction given in the question step by step. ### Step-by-Step Solution: 1. **Identify the Reactants:** The reactant in the reaction is Benzaldehyde, which has the formula C₆H₅CHO. The other reactant is Hydroxylamine (NH₂OH). 2. **Understand the Reaction Type:** Benzaldehyde is a carbonyl compound (an aldehyde), and it reacts with Hydroxylamine, which is a derivative of ammonia. This type of reaction typically leads to the formation of an oxime. 3. **Reaction Mechanism:** In the reaction, the carbonyl group (C=O) of benzaldehyde reacts with the hydroxylamine. The nitrogen from hydroxylamine attacks the carbon atom of the carbonyl group, leading to the formation of a tetrahedral intermediate. 4. **Elimination of Water:** The tetrahedral intermediate will then undergo dehydration (loss of water). The oxygen atom from the carbonyl group (C=O) will be eliminated along with a hydrogen atom from the hydroxylamine, resulting in the formation of water (H₂O). 5. **Formation of the Product:** After the elimination of water, the product formed will be an oxime. The structure of the product can be represented as: \[ C₆H₅C=N-OH \] This compound has a double bond between carbon and nitrogen, with a hydroxyl group (–OH) attached to the nitrogen. 6. **Geometric Isomerism:** The product can exhibit geometric isomerism (cis/trans or E/Z isomerism) due to the presence of the double bond between carbon and nitrogen. The possible isomers are: - **Syn-oxime**: where the hydroxyl group and the phenyl group are on the same side. - **Anti-oxime**: where the hydroxyl group and the phenyl group are on opposite sides. 7. **Conclusion:** The final product of the reaction is an oxime, specifically a mixture of syn-oxime and anti-oxime. Therefore, the correct answer to the question is the oxime derived from benzaldehyde. ### Final Answer: The product [x] will be an oxime, specifically a mixture of syn-oxime and anti-oxime.
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