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In the reaction X + Y underset(5^(@)...

In the reaction
X + Y `underset(5^(@)C)overset(NaOH)(rarr) CH_(3)-overset(OH)overset(|)(CH)-underset(CH_(3))underset(|)(CH)-CHO`
(X) and (Y) Will respectively be :

A

`CH_(3)–CH_(2)`–CHO and `CH_(3)–CH_(2)`–CHO

B

`CH_(3)`–CHO and `CH_(3)–CH_(2)`–CHO

C

`CH_(3)`–CHO and `CH_(3)`–CHO

D

`CH_(3)`-CHO and `CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C ) - CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the reactants X and Y in the given reaction, we need to analyze the product formed and the conditions under which the reaction occurs. The product is a result of aldol condensation, which typically involves the reaction of two aldehydes or ketones in the presence of a base. ### Step-by-Step Solution: 1. **Identify the Product**: The product given is CH3-CH(OH)-CH(CH3)-CHO. This structure indicates that it is a β-hydroxy aldehyde, which is a common intermediate in aldol condensation reactions. 2. **Understand Aldol Condensation**: Aldol condensation occurs when two carbonyl compounds (aldehydes or ketones) react in the presence of a base (like NaOH) to form a β-hydroxy carbonyl compound, which can further dehydrate to form an α,β-unsaturated carbonyl compound. 3. **Analyze the Structure of the Product**: The product has: - A hydroxyl group (-OH) attached to the second carbon (β-position). - An aldehyde group (-CHO) at the end of the carbon chain. - Two methyl groups (CH3) indicating that one of the reactants must be a compound that can provide these groups. 4. **Determine Possible Reactants**: - The presence of the aldehyde group suggests that one of the reactants is likely an aldehyde. - The other reactant must also be a carbonyl compound capable of forming the β-hydroxy aldehyde. 5. **Choose Reactants**: - Let's consider the reactants CH3CHO (acetaldehyde) and CH3CH2CHO (butanal). - When CH3CHO reacts with CH3CH2CHO in the presence of NaOH, the aldol condensation can occur. 6. **Reaction Mechanism**: - The base (NaOH) will deprotonate the alpha hydrogen of one of the aldehydes, forming an enolate ion. - This enolate will then attack the carbonyl carbon of the other aldehyde, leading to the formation of the β-hydroxy aldehyde. 7. **Final Verification**: - The product formed from the reaction of CH3CHO and CH3CH2CHO matches the given product structure, confirming that these are indeed the correct reactants. ### Conclusion: Thus, the reactants X and Y are: - **X = CH3CHO (Acetaldehyde)** - **Y = CH3CH2CHO (Butanal)**
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MOTION-CARBONL COMPOUNDS-EXERCISE - 2 (LEVEL -I)
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