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CH(3) - overset(O)overset(||)(C ) - CH(3...

`CH_(3) - overset(O)overset(||)(C ) - CH_(3) + H - overset(O)overset(||)(C ) - H " "overset(KOH)(rarr)`
(A) major. Product (A) is :

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction, we need to analyze the components and the reaction conditions. The reaction involves a ketone (acetone) and formaldehyde in the presence of a strong base (KOH). ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are acetone (CH₃COCH₃) and formaldehyde (HCHO). - The presence of KOH indicates that we are dealing with a base-catalyzed reaction. 2. **Understand the Role of KOH**: - KOH is a strong base that will deprotonate the α-hydrogen of acetone. - This results in the formation of an enolate ion from acetone. 3. **Formation of the Enolate Ion**: - The α-hydrogen of acetone (the hydrogen attached to the carbon adjacent to the carbonyl group) is acidic and can be removed by OH⁻. - The resulting enolate ion has a negative charge on the carbon adjacent to the carbonyl group. 4. **Nucleophilic Attack**: - The enolate ion acts as a nucleophile and attacks the carbonyl carbon of formaldehyde. - This step forms a tetrahedral intermediate. 5. **Proton Transfer**: - After the nucleophilic attack, the tetrahedral intermediate collapses, leading to the formation of a new carbon-carbon bond. - The hydroxyl group (OH) from the intermediate can be protonated to form water (H₂O). 6. **Final Product Formation**: - The final product of this reaction is a β-hydroxy ketone. - The structure of the product will be: CH₃C(OH)(CH₂CHO)CH₃, which can be simplified to a compound with a hydroxyl group and a carbonyl group. 7. **Conclusion**: - The major product (A) of the reaction is a β-hydroxy ketone formed from the condensation of acetone and formaldehyde. ### Final Answer: The major product (A) is: **CH₃C(OH)(CH₂CHO)CH₃** (β-hydroxy ketone).
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