Home
Class 12
CHEMISTRY
A 5 percent aqueous solution by mass of ...

A 5 percent aqueous solution by mass of a non-volatile solute boils at 100.`15^@C`. Calculate the molar mass of the solute. `K_b = 0.52 K kg mol^(-1)`.

Text Solution

Verified by Experts

The normal boiling point of water is `100^@C`.
`:.` The elevation in boiling point is `0.15^@C`.
A 5 percent solution means that in a 100 g solution 5 g of the solute is present. This implies that the solvent is 95 g.
If the molar mass of the solute is M, then the molality of the solute in the solution is,
`(5//M)/95xx1000,DeltaT_b=K_bm`
`0.15=0.52xx(5//m)/95xx1000`
`:.` M = 182.4 g/mol
Promotional Banner

Topper's Solved these Questions

  • LIQUID SOLUTION

    MOTION|Exercise EXERCISE-1 OBJECTIVE PROBLEMS JEE MAIN|68 Videos
  • LIQUID SOLUTION

    MOTION|Exercise EXERCISE-2 (LEVEL -I) OBJECTIVE PROBLEMS JEE MAIN|53 Videos
  • ISOMERISM

    MOTION|Exercise Exercise 4|26 Videos
  • METALLURGY

    MOTION|Exercise EXERCISE 4 (LEVEL - II)|17 Videos

Similar Questions

Explore conceptually related problems

A 5 per cent aqueous solution by mass of a non-volatile solute boils at 100.15^(@)C . Calculate the molar mass of the solute. K_(b)=0.52 K kg "mol"^(-1) .

An aqueous dilute solution containing non- volatile solute boils at 100.052 ""^(@) C what is the molality of solution ? K_(b) = 0.52 kg mol ^(-1) K, Boiling temperature of water =100^(@) C )

A 0.2 percent aqueous solution of a non-volatile solute exerts a vapour pressure of 1.004 bar at 100^(@)C . What is the molar mass of the solute ? (Given : vapour pressure of pure water at 100^(@)C is 1.013 bar and molar mass of water is "18 g mol"^(-1) )

An aqueous solution of a non-volatile solute boils at 100.17^(@)C . At what temperature will the solution freeze? (Given: K_(b) = 0.512 and K_(f) = 1.86 )

The boiling point of water (100^(@)C) becomes 100.52^(@) C if 3 g of a non - volatile solute is dissolved in 20 ml of it . Calculate the molar mass of the solute ( k_(b) for water = 0.52 K m^(-1) ).

MOTION-LIQUID SOLUTION-EXERCISE-4 (Level-II) PREVIOUS YEAR JEE ADVANCED
  1. A 5 percent aqueous solution by mass of a non-volatile solute boils at...

    Text Solution

    |

  2. 1.22 g of benzoic acid is dissolved in (i) 100g acetone (K(b) for acet...

    Text Solution

    |

  3. The elevation in boiling point, when 13.44 g of freshly prepared CuCI(...

    Text Solution

    |

  4. 72.5g of phenol is dissolved in 1kg of a solvent (k(f) = 14) which lea...

    Text Solution

    |

  5. When 20 g of naphthoic acid (C(11)H(8)O(2)) is dissolved in 50 g of be...

    Text Solution

    |

  6. The freezing point of the solution M is

    Text Solution

    |

  7. The vapour pressure of the solution M is

    Text Solution

    |

  8. Water is added to the solution M such that the mole fraction of water ...

    Text Solution

    |

  9. The Henry's law constant for the solubility of N(2) gas in water at 29...

    Text Solution

    |

  10. The freezing point (in .^(@)C) of a solution containing 0.1g of K(3)[F...

    Text Solution

    |

  11. For a dilute solution containing 2.5 g of a non-volatile non-electroly...

    Text Solution

    |

  12. Benzene and naphthalene form an ideal solution at room temperature. Fo...

    Text Solution

    |

  13. MX(2) dissociates into M^(2+) and X^(ө) ion in an aqueous solution, wi...

    Text Solution

    |

  14. A compound H(2)X with molar weigth of 80g is dissolved in a solvent ha...

    Text Solution

    |

  15. If the freezing point of a 0.01 molal aqueous solution of a cobalt (II...

    Text Solution

    |

  16. Mixture (s) showing positive deviation from Raoult's law at 35^(@)C is...

    Text Solution

    |

  17. For a solution formed by mixing liquids L and M, the vapour pressure o...

    Text Solution

    |

  18. Pure water freezes at 273 K and 1 bar. The addition of 34.5 g of ethan...

    Text Solution

    |

  19. The plot given below shows P -T curves (where P is the pressure and T ...

    Text Solution

    |

  20. Liquids A and B form ideal solution over the entire range of compositi...

    Text Solution

    |