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Statement - I. Greater the molal depress...

Statement - I. Greater the molal depression constant of the solvent used less in the freezing point of the solution.
Statement - II. Depression in freezing point depends upon the nature of the solvent.

A

Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.

B

Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.

C

Statement-1 is true, statement-2 is false.

D

Statement-1 is false, statement-2 is true.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the statements provided in the question, we will break down each statement step by step. ### Step 1: Analyze Statement I **Statement I**: "Greater the molal depression constant of the solvent used less in the freezing point of the solution." - The molal depression constant (Kf) is a property of the solvent that indicates how much the freezing point of the solvent will decrease when a solute is added. - The relationship can be expressed as: \[ \Delta T_f = K_f \times m \] where \(\Delta T_f\) is the depression in freezing point and \(m\) is the molality of the solution. - If the value of Kf is greater, it means that for the same molality, the depression in freezing point (\(\Delta T_f\)) will be greater. Therefore, a greater Kf leads to a greater depression in freezing point, not less. **Conclusion for Statement I**: This statement is **False**. ### Step 2: Analyze Statement II **Statement II**: "Depression in freezing point depends upon the nature of the solvent." - The depression in freezing point is a colligative property, which means it depends on the number of solute particles in the solution, not on the nature of the solvent. - The formula for depression in freezing point is: \[ \Delta T_f = K_f \times m \] Here, Kf is a constant for a specific solvent, but the depression itself does not depend on the type of solvent used; it depends on the concentration (molality) of the solute. - Therefore, the nature of the solvent does not affect the depression in freezing point. **Conclusion for Statement II**: This statement is **False**. ### Final Conclusion - Statement I is **False**. - Statement II is **False**.
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