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Column I (A) Ideal solution (B) Solu...

Column I
(A) Ideal solution
(B) Solutions showing positive deviations
(C) Solutions showing negative deviations
Column II
(P) Solute-solvent interactions are weaker than solute-solute
(Q) Solute-solvent interactions are similar to solutesolute
(R) Solute-solvent interactions are stronger than solute-solute interactions

Text Solution

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The correct Answer is:
To solve the problem of matching the solutions from Column I with the interactions from Column II, we will analyze each type of solution and its corresponding interactions step by step. ### Step 1: Identify the Characteristics of Each Solution Type 1. **Ideal Solution (A)**: - In an ideal solution, the interactions between solute-solvent are similar to those between solute-solute and solvent-solvent. This means that the vapor pressure of the solution follows Raoult's law perfectly. - Therefore, the correct match for ideal solution is **(Q)**: Solute-solvent interactions are similar to solute-solute interactions. 2. **Solutions Showing Positive Deviations (B)**: - In solutions showing positive deviations, the vapor pressure of the solution is higher than expected. This occurs when the solute-solvent interactions are weaker than the solute-solute interactions. - Hence, the correct match for positive deviations is **(P)**: Solute-solvent interactions are weaker than solute-solute interactions. 3. **Solutions Showing Negative Deviations (C)**: - In solutions showing negative deviations, the vapor pressure of the solution is lower than expected. This happens when the solute-solvent interactions are stronger than the solute-solute interactions. - Thus, the correct match for negative deviations is **(R)**: Solute-solvent interactions are stronger than solute-solute interactions. ### Step 2: Summarize the Matches Now, we can summarize the matches as follows: - **A (Ideal solution)** → **Q (Solute-solvent interactions are similar to solute-solute interactions)** - **B (Solutions showing positive deviations)** → **P (Solute-solvent interactions are weaker than solute-solute interactions)** - **C (Solutions showing negative deviations)** → **R (Solute-solvent interactions are stronger than solute-solute interactions)** ### Final Answer: - A → Q - B → P - C → R ---
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