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The product P of the following reaction ...

The product P of the following reaction is
`CH_(3)-COOHoverset(LiAlH_(4))to overset(SOCl_(2))to overset(14)overset(KCN)to overset(H_(3)O^(o+))toP`

A

`CH_(3)-COOH`

B

`CH_(3)-CH_(2)-overset(14)COOH`

C

`CH_(3)-overset(14)COOH`

D

`CH_(3)-overset(14)CH_(2)-COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction step by step, we will analyze each stage of the reaction involving the carboxylic acid (acetic acid, CH₃COOH) and the reagents used. ### Step 1: Reduction of Carboxylic Acid The first step involves the reduction of acetic acid (CH₃COOH) using lithium aluminum hydride (LiAlH₄). - **Reaction**: \[ CH₃COOH + LiAlH₄ \rightarrow CH₃CH₂OH \] - **Product**: Ethanol (CH₃CH₂OH) ### Step 2: Reaction with Sulfonyl Chloride Next, the ethanol reacts with thionyl chloride (SOCl₂). - **Reaction**: \[ CH₃CH₂OH + SOCl₂ \rightarrow CH₃CH₂Cl + SO₂ + HCl \] - **Product**: Ethyl chloride (CH₃CH₂Cl) ### Step 3: Reaction with KCN The ethyl chloride (CH₃CH₂Cl) then reacts with potassium cyanide (KCN). - **Reaction**: \[ CH₃CH₂Cl + KCN \rightarrow CH₃CH₂CN + KCl \] - **Product**: Propionitrile (CH₃CH₂CN) ### Step 4: Hydrolysis of Nitrile Finally, the propionitrile (CH₃CH₂CN) undergoes hydrolysis in the presence of water (H₂O) and an acid (H₃O⁺). - **Reaction**: \[ CH₃CH₂CN + H₂O \xrightarrow{H^+} CH₃CH₂COOH + NH₃ \] - **Product**: Propanoic acid (CH₃CH₂COOH) ### Final Product The final product \( P \) of the entire reaction sequence is propanoic acid (CH₃CH₂COOH). ### Summary of the Steps: 1. **Reduction**: Carboxylic acid to alcohol (Ethanol). 2. **Conversion**: Alcohol to alkyl halide (Ethyl chloride). 3. **Nucleophilic Substitution**: Alkyl halide to nitrile (Propionitrile). 4. **Hydrolysis**: Nitrile to carboxylic acid (Propanoic acid). ### Final Answer The product \( P \) is **Propanoic acid (CH₃CH₂COOH)**. ---
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