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In the given reaction sequene : C(6)H(...

In the given reaction sequene :
`C_(6)H_(5)-CN overset((H_(2)O)//overset(o+)(H)//Delta)toA overset(SOCl_(2))toB overset(C_(6)H_(6)//AlCl_(3))toC`, (C) is

A

`C_(6)H_(5)-overset(O)overset(||)C-C_(6)H_(5)`

B

`C_(6)H_(5)-overset(O)overset(||)C-O-C_(6)H_(5)`

C

`C_(6)H_(5)-overset(O)overset(||)C-NH-C_(6)H_(5)`

D

`C_(6)H_(5)-overset(O)overset(||)C-O-C_(6)H_(5)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction sequence, we need to identify the compounds A, B, and C step by step. Let's break down the reaction sequence provided: 1. **Starting Compound**: The starting compound is **C6H5CN** (benzonitrile). 2. **Step 1 - Hydrolysis of Benzonitrile**: - When benzonitrile (C6H5CN) is treated with water (H2O) and heat, it undergoes hydrolysis. - The nitrile group (CN) is converted into a carboxylic acid (COOH). - The product formed is **benzoic acid (C6H5COOH)**. - Therefore, **A = C6H5COOH**. 3. **Step 2 - Reaction with Thionyl Chloride (SOCl2)**: - Benzoic acid (A) reacts with thionyl chloride (SOCl2) to convert the carboxylic acid group into an acyl chloride. - The reaction replaces the hydroxyl group (OH) of the carboxylic acid with a chlorine atom (Cl). - The product formed is **benzoyl chloride (C6H5COCl)**. - Therefore, **B = C6H5COCl**. 4. **Step 3 - Friedel-Crafts Acylation**: - Benzoyl chloride (B) is then reacted with benzene (C6H6) in the presence of aluminum chloride (AlCl3), which acts as a Lewis acid. - This reaction is known as Friedel-Crafts acylation, where the acyl group from benzoyl chloride is introduced into the benzene ring. - The product formed is **acetophenone (C6H5COC6H5)**. - Therefore, **C = C6H5COC6H5**. ### Final Answer: C = Acetophenone (C6H5COC6H5)
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