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X overset(NH(3)//Delta)toB underset(Delt...

`X overset(NH_(3)//Delta)toB underset(Delta)overset(KOBr)to overset(HNO_(2))to(CH_(3))_(3)C-OH,X` is :

A

`(CH_(3))_(3)C-COOH`

B

`(CH_(3))_(3)C-CH_(2)O`

C

`(CH_(3))_(3)C-CONH_(2)`

D

none is true

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The correct Answer is:
To solve the question `X overset(NH_(3)//Delta)toB underset(Delta)overset(KOBr)to overset(HNO_(2))to(CH_(3))_(3)C-OH,X`, we will analyze the sequence of reactions step by step. ### Step 1: Identify the structure of compound B The first step involves treating compound X with ammonia (NH₃) under heat (Δ). Given that X is a carboxylic acid, we can represent it as: \[ \text{X} = \text{RCOOH} \] where R is a hydrocarbon chain. The reaction of a carboxylic acid with ammonia under heat typically leads to the formation of an amide: \[ \text{RCOOH} + \text{NH}_3 \xrightarrow{\Delta} \text{RCONH}_2 + \text{H}_2\text{O} \] Thus, compound B will be: \[ \text{B} = \text{RCONH}_2 \] This is a primary amide. ### Step 2: Reaction of B with KOBr Next, compound B (the primary amide) is treated with KOBr (potassium hypobromite). This is known as the Hofmann degradation reaction, which converts primary amides to primary amines: \[ \text{RCONH}_2 + \text{KOBr} \xrightarrow{\Delta} \text{RNH}_2 + \text{CO}_2 + \text{HBr} \] Thus, the product after this reaction will be: \[ \text{C} = \text{RNH}_2 \] This is a primary amine. ### Step 3: Reaction of C with HNO₂ The primary amine C is then treated with nitrous acid (HNO₂). The reaction of a primary amine with nitrous acid leads to the formation of an alcohol and nitrogen gas: \[ \text{RNH}_2 + \text{HNO}_2 \rightarrow \text{R-OH} + \text{N}_2 + \text{H}_2\text{O} \] Thus, the final product after this reaction will be: \[ \text{(CH}_3)_3\text{C-OH} \] This indicates that R is a tert-butyl group (C₄H₉). ### Conclusion From the above steps, we can conclude that compound X is: \[ \text{X} = \text{(CH}_3)_3\text{C-COOH} \] This is the carboxylic acid corresponding to the tert-butyl alcohol formed at the end of the reaction sequence. ### Final Answer X is **tert-butanoic acid** (or 2-methylpropanoic acid).
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Give the structures of A, B and C in the following reactions: (i) CH_(3)Br overset(KCN)(to) A overset(LiAlH_(4))(to) B underset(273 K)overset(HNO_(2))(to) C (ii) CH_(3)COOH underset(Delta)overset(NH_(3))(to) A overset(Br_(2)+KOH)(to) B overset(CHCl_(3)+NaOH)(to) C (iii) CH_(3)CN overset(H_(2)O"/"OH^(-))(to) A underset(Delta)overset(NH_(3))(to)B overset(Br_(2)+KOH)(to) C

Give the structures of A, B and C in the following reactions (i) CH_(3)CH_(2)I overset(NaCN)(to) A underset("hydrolysis Partial")overset(OH^(-))(to) B overset(NaOH+Br_(2))to C (ii) C_(6)H_(5)N_(2)Cl overset(CuCN)to A overset(H_(2)O // H^(+))(to) B underset(Delta)overset(NH_(3))(to) C (iii) CH_(3)CH_(2)Br overset(KCN)to A overset(LiAlH_(4))to B underset(0^(@)C)overset(HNO_(2))to C (iv) C_(6)H_(5)NO_(2) overset(Fe//HCl)to A underset(273 K)overset(NaNO_(2)+HCl)to B underset(Delta)overset(H_(2)O // H^(+))to C (v) CH_(3)COOH underset(Delta)overset(NH_(3))to A overset(NaOBr)to B overset(NaNO_(2)//HCl)to C (vi) C_(6)H_(5)NO_(2) overset(Fe//HCl)to A underset(273 K)overset(HNO_(2))to B overset(C_(6)H_(5)OH)to C

Give the structures of the products A, B and C in the following reactions: (i) CH_(3)CH_(2)Br overset(KCN)(to) A overset(LiAlH_(4))(to) B underset(0^(@)C)overset(HNO_(2))(to) C (ii) CH_(3)COOH underset(Delta)overset(NH_(3))(to) A overset(NaOH + Br_(2))(to) B overset(CHCl_(3) + alc KOH)(to) C

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Which of the following will produce isopropyl amine - (I) (CH_(3))_(2)CO overset(NH_(2)OH)rarr X overset(LiAlH_(4))rarr (II) CH_(3)-CH_(2)-CHO overset(NH_(3))underset("heat")rarr X overset(LiAlH_(4))rarr (III) (CH_(3))_(2)CH-OH+PCl_(5)rarr X overset(NH_(3))rarr (IV) CH_(3)-CH_(2)-CH_(2)-NH_(2)overset("heat")rarr

MOTION-CARBOXYLIC ACID-Exercise - 2(LEVEL - 2)
  1. Following will not yield a cyclic compound on heating :

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  2. In the following reaction X overset(Delta)to Y. X is the lowest molecu...

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  3. X overset(NH(3)//Delta)toB underset(Delta)overset(KOBr)to overset(HNO(...

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  4. PhCH(2)-overset(CH(3))overset(|)(CH)-CH(2)-overset(O)overset(||)C-NH(2...

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  5. Product X & Y are :–

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  6. Urea (H(2)NCONH(2))+ hot dilute NaOH to X+NH(3), X is

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  9. The increasing order of basicity of RCN,RCH=NR and RNH(2) is :-

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  10. How many isomeric amines with formula C(7)H(9)N contain a benzene ring...

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  11. in which of the following reaction, Amine is obtained as a product.

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  12. Reaction of RCONH(2) with a mixture of Br(2) and KOH gives RNH(2) as t...

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  13. Amines are highly soluble in

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  14. Which of the following reagents can be used to convert benzenediazoniu...

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  15. The bromination of aniline in presence of water produces :

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  16. The compound which on rection with aqueous nirous acid at low temperat...

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  17. Carbylamine test is performed in alcoholic KOH by heating a mixture of...

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  18. Activation of benzene by -NH2 group can be reduced by treating the com...

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  19. Dipolar ion structure for amino acid is

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  20. -NH(2) group shows acidic nature while reacts with reagent.

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