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The correct reagent sequence for the fol...

The correct reagent sequence for the following conversion
`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-Br to CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-COOH`, is

A

`overset(KCN)to underset(Delta)overset(H_(3)O^(o+))to`

B

`overset(Mg//"ether")to overset(CO_(2))to overset(H^(o+))to`

C

`overset(Mg//"ether")to overset(Cl-COOH)to`

D

`overset(Mg//"ether")to underset(1.eq.)overset(HCOCl)tounderset(1.eq.)overset(KMnO_(4)//OH^("Θ"))to`

Text Solution

AI Generated Solution

The correct Answer is:
To convert the compound CH3-C(CH3)2-Br to CH3-C(CH3)2-COOH, we need to follow a series of steps involving specific reagents. Here’s a step-by-step breakdown of the process: ### Step 1: Nucleophilic Substitution 1. **Reagent:** KCN (Potassium cyanide) - The bromine (Br) atom in the starting compound is a good leaving group. When KCN is added, the Br leaves, forming a tertiary carbocation. - The cyanide ion (CN-) then attacks the carbocation, resulting in the formation of CH3-C(CH3)2-CN. ### Step 2: Hydrolysis of Nitrile 2. **Reagent:** H2O (Water) in acidic medium - The nitrile (CN) undergoes hydrolysis in the presence of water and an acid (like HCl) to convert it into a carboxylic acid. - The CN group is converted into a carboxylic acid (COOH) through the formation of an intermediate amide, which is then hydrolyzed to yield CH3-C(CH3)2-COOH. ### Summary of Reagents - The correct sequence of reagents for the conversion is: 1. KCN (to form the nitrile) 2. H2O (in acidic medium for hydrolysis) ### Final Product - The final product is CH3-C(CH3)2-COOH, which is a carboxylic acid.
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MOTION-CARBOXYLIC ACID-Exercise - 2(LEVEL - 2)
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