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The structure of XeF2 involves hybrdizat...

The structure of `XeF_2` involves hybrdization of the type :

A

`sp^3`

B

`dsp^3`

C

`sp^3d`

D

`sp^3d^2`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the type of hybridization in the structure of \( \text{XeF}_2 \), we can follow these steps: ### Step 1: Determine the Valence Electrons - **Xenon (Xe)** is a noble gas with 8 valence electrons. - **Fluorine (F)** has 7 valence electrons, but in \( \text{XeF}_2 \), each fluorine atom will form one bond with xenon, using 1 electron from xenon for each bond. ### Step 2: Calculate the Total Electrons Used in Bonding - Since there are 2 fluorine atoms, xenon will use 2 of its valence electrons to form 2 bond pairs with fluorine. ### Step 3: Calculate Remaining Electrons - After forming the 2 bonds, xenon will have \( 8 - 2 = 6 \) valence electrons left. - These remaining 6 electrons will be arranged as lone pairs. ### Step 4: Determine the Number of Lone Pairs - The 6 remaining electrons will form 3 lone pairs (since each lone pair consists of 2 electrons). ### Step 5: Calculate the Steric Number - The steric number is calculated as the sum of the number of bond pairs and lone pairs. - Here, we have 2 bond pairs (from the bonds with fluorine) and 3 lone pairs: \[ \text{Steric Number} = \text{Number of Bond Pairs} + \text{Number of Lone Pairs} = 2 + 3 = 5 \] ### Step 6: Determine the Hybridization - A steric number of 5 corresponds to \( \text{sp}^3\text{d} \) hybridization. ### Step 7: Determine the Geometry and Shape - The geometry of \( \text{XeF}_2 \) is trigonal bipyramidal due to the \( \text{sp}^3\text{d} \) hybridization. - However, the shape is linear because the three lone pairs occupy the equatorial positions, leaving the two fluorine atoms at the axial positions. ### Conclusion The hybridization of \( \text{XeF}_2 \) is \( \text{sp}^3\text{d} \). ---
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