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Stability of the species Li(2), Li(2)^(-...

Stability of the species `Li_(2), Li_(2)^(-)` and `Li_(2)^(+)` increases in the order of

A

`Li_2 lt Li_2^+ lt Li_2^-`

B

`Li_2^(-) lt Li_2^+ lt Li_2 `

C

`Li_2 lt Li_2^(-) lt Li_2^+`

D

`Li_2^(-) lt Li_2 lt Li_2^+`

Text Solution

Verified by Experts

The correct Answer is:
B

`Li_2` (3+3=6)=`sigma1s^2 sigma**1s^2 ,sigma2s^2`
Bond order = `(N_b-N_a)/2 =(4-2)/2=1`
`Li_2^+` (3+1-1=5) = `sigma1s^2 , sigma**1s^2 , sigma2s^2 , sigma**2s^1`
Bond order = `(3-2)/2=1/2=0.5`
`Li_2^(-) ` (3+3+1=7) = `sigma1s^2 , sigma**1s^2 , sigma2s^2 , sigma**2s^1`
Bond order =`(4-3)/2=1/2`=0.5
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