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3-methyl-3-hexanol can be prepared by -...

3-methyl-3-hexanol can be prepared by -

A

`CH_3Mgl` and 3-hexanone, followed by hydrolysis

B

`C_2H_5 Mgl` and 2-Pentanone, followd by hydrolysis

C

`C_3H_7 Mgl` and 2-butananone, followd by hydrolysis

D

`C_4 H_9 Mgl` and propanon, followed by hydrolysis

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To prepare 3-methyl-3-hexanol, we can follow these steps: ### Step 1: Identify the structure of 3-methyl-3-hexanol 3-methyl-3-hexanol has the following structure: - It is a hexanol (6 carbon atoms) with a methyl group (CH3) attached to the third carbon. - The hydroxyl group (OH) is also on the third carbon. ### Step 2: Choose a suitable starting material A suitable starting material for the synthesis of 3-methyl-3-hexanol is 2-pentanone. This ketone has five carbon atoms and can be reacted with a Grignard reagent to introduce the additional methyl group. ### Step 3: Prepare the Grignard reagent To introduce the methyl group, we can prepare a Grignard reagent from methyl iodide (CH3I) and magnesium (Mg). The reaction is as follows: \[ \text{CH}_3\text{I} + \text{Mg} \rightarrow \text{CH}_3\text{MgI} \] This Grignard reagent (CH3MgI) will act as a nucleophile in the next step. ### Step 4: React the Grignard reagent with 2-pentanone Now, we will react the prepared Grignard reagent (CH3MgI) with 2-pentanone (C5H10O). The reaction is: \[ \text{CH}_3\text{MgI} + \text{C}_5\text{H}_{10}\text{O} \rightarrow \text{C}_6\text{H}_{14}\text{O} + \text{MgI(OH)} \] In this reaction, the nucleophilic methyl group from the Grignard reagent attacks the carbonyl carbon of 2-pentanone, forming an alkoxide intermediate. ### Step 5: Hydrolyze the alkoxide The alkoxide intermediate formed in the previous step can be hydrolyzed by adding water (H2O): \[ \text{C}_6\text{H}_{14}\text{O} + \text{H}_2\text{O} \rightarrow \text{3-methyl-3-hexanol} + \text{Mg(OH)I} \] This hydrolysis step converts the alkoxide into the desired alcohol, 3-methyl-3-hexanol. ### Final Structure The final product is 3-methyl-3-hexanol, which has the following structure: - A hydroxyl group (OH) on the third carbon. - A methyl group (CH3) also on the third carbon. ### Summary Thus, 3-methyl-3-hexanol can be prepared by the following sequence: 1. Synthesize the Grignard reagent (CH3MgI). 2. React it with 2-pentanone to form an alkoxide. 3. Hydrolyze the alkoxide to obtain 3-methyl-3-hexanol. ---
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MOTION-ALCOHOLS & ETHERS-EXERCISE -2 (LEVEL -II) MULTIPLE CORRECT JEE ADVANCED
  1. Which of the following compound undergo hydrolysis most easily :

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  2. Which can be cleaved by HIO4 ?

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  3. Explain esterification reaction.

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  4. overset(H2//Pd//BaSO4)to (Z) Identify X, Y, Z :

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  5. Which is/are corect statement ?

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  6. 3-methyl-3-hexanol can be prepared by -

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  7. Which compound will be oxidised by HIO(4) ?

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  8. Which of the following is/are aromatic ?

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  9. Acctaldehyde can be obtained from which of the following rections ?

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  10. Find out number of alcohols that can give positive iodoform test.

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  11. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  12. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  13. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  14. Carbon oxygen double bond are easily reduced by NaBH(4) or LiAlH(4). T...

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  15. Carbon oxygen double bond are easily reduced by NaBH(4) or LiAlH(4). T...

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  16. Acid catalysed conversation of 1,2-diol or vicinal, into carbonyl comp...

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  17. Acid catalysed conversion of 1,2-diol or vicinal diol, into carbonyl c...

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  18. Column - I (A) Oxidation of 1^@ alcohol in aldehyde Oxidation ...

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  19. Column- I (A) Identification of 1^@, 2^@ and 3^@ alcohol (B) Ident...

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  20. Column - I (A) CH3-overset(O)overset(||)-O-overset(Ph)overset(|)unde...

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