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Column - I (A) CH3-overset(O)overset(|...

Column - I
(A) `CH_3-overset(O)overset(||)-O-overset(Ph)overset(|)underset(Ph)underset(|)-Phoverset(H^(oplus)//H_2O)to`
(B) `CH_3-overset(CH_3)overset(|)underset(CH_3)underset(|)-overset(O)overset(||)C-o-Ph overset(H^(oplus)//H_2O)to `
(C ) `CH_3-O- overset(CH_3)overset(|)underset(CH_3)underset(|)C-CH_3 overset(H^(oplus)//H_2O)to`
(D) `CH_3-O-underset(CH_3)underset(|)CH-CH_3 overset(HI)to`
Column-II
(P) Unimolecular
(Q) Bimolecular
(R) Alkyl oxygen bond cleavage
(S) Acyl oxygen bond cleavage

Text Solution

Verified by Experts

The correct Answer is:
(A)-P,R;(B)-P,S;(C )-P,R;(D) Q,R
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The IUPAC name of CH_(3)-overset(OH)overset(|)underset(H)underset(|)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3) is:

CH_(3)-underset(CH_(3))underset(|)(CH)-CH=CH-CH_(2)-overset(O)overset(||)(C)-OH

CH_(3)-overset(O)overset(||)(C)-CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CHOoverset(KOH,H_(2)O)to(A) , product A is

IUPAC name of CH_3-underset(C_2H_5)underset(|)overset(H)overset(|)C-underset(CH_3)underset(|)overset(C_4H_9)overset(|)C-CH_3 is

CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(2)-underset(O)underset(||)(C)-NHCH_(3)

Write IUPAC Name : (a) CH_(3)-CH_(2)-underset(CH_(3))underset(|)underset(CH_(2))underset(|)CH-overset(O)overset(||)C-OCH_(3) (b) CH_(3)-underset(" "CH=CH_(2))underset(|)(CH)-CH_(2)-overset(O)overset(||)C-OC_(2)H_(5) (c) > CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)C-overset(" "overset(O)overset(||)C-NH_(2))overset(|)(CH)-underset(CH_(3))underset(|)(CH)-CH_(3)

The two compound may be considered as : CH_(3)=overset(O)overset(||)(C)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-CH_(3) and CH_(3)-overset(CH_(3))overset(|)(CH)-overset(O)overset(||)(C)-CH_(2)CH_(3)

CH_(3)-overset(CH_(3))overset("| ")"CH"-underset(O)underset(|)C-O-overset(CH_(3))overset("| ")underset(CH_(3))underset("| ")"C "-CH_(3) The common name of given ester is -

MOTION-ALCOHOLS & ETHERS-EXERCISE -2 (LEVEL -II) MULTIPLE CORRECT JEE ADVANCED
  1. Which of the following compound undergo hydrolysis most easily :

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  2. Which can be cleaved by HIO4 ?

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  3. Explain esterification reaction.

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  4. overset(H2//Pd//BaSO4)to (Z) Identify X, Y, Z :

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  5. Which is/are corect statement ?

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  6. 3-methyl-3-hexanol can be prepared by -

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  7. Which compound will be oxidised by HIO(4) ?

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  8. Which of the following is/are aromatic ?

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  9. Acctaldehyde can be obtained from which of the following rections ?

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  10. Find out number of alcohols that can give positive iodoform test.

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  11. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  12. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  13. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  14. Carbon oxygen double bond are easily reduced by NaBH(4) or LiAlH(4). T...

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  15. Carbon oxygen double bond are easily reduced by NaBH(4) or LiAlH(4). T...

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  16. Acid catalysed conversation of 1,2-diol or vicinal, into carbonyl comp...

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  17. Acid catalysed conversion of 1,2-diol or vicinal diol, into carbonyl c...

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  18. Column - I (A) Oxidation of 1^@ alcohol in aldehyde Oxidation ...

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  19. Column- I (A) Identification of 1^@, 2^@ and 3^@ alcohol (B) Ident...

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  20. Column - I (A) CH3-overset(O)overset(||)-O-overset(Ph)overset(|)unde...

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