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It takes 2.56xx10^(-3) equivalents of KO...

It takes `2.56xx10^(-3)` equivalents of `KOH` to neutralize 0.1254g `H_2 XO_4` where X is a non-metal. The number of neutrons in X are:

A

16

B

8

C

7

D

32

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the number of neutrons in the non-metal X in the compound \( H_2XO_4 \) given that it takes \( 2.56 \times 10^{-3} \) equivalents of KOH to neutralize \( 0.1254 \, \text{g} \) of \( H_2XO_4 \). ### Step-by-Step Solution: 1. **Identify the Acid and Its Properties**: - The compound \( H_2XO_4 \) is an acid that can donate protons (H⁺ ions). When it dissociates, it produces 2 H⁺ ions and the anion \( XO_4^{2-} \). 2. **Determine the Moles of KOH Used**: - Given that \( 2.56 \times 10^{-3} \) equivalents of KOH are used, and knowing that KOH has an n-factor of 1 (it provides 1 OH⁻ ion per molecule), we can directly equate equivalents to moles: \[ \text{Moles of KOH} = 2.56 \times 10^{-3} \, \text{moles} \] 3. **Relate Moles of KOH to Moles of H⁺**: - Since 2 moles of OH⁻ are needed to neutralize 2 moles of H⁺, the moles of H⁺ produced from \( H_2XO_4 \) will also be: \[ \text{Moles of H}^+ = 2.56 \times 10^{-3} \, \text{moles} \] 4. **Calculate Moles of \( H_2XO_4 \)**: - The stoichiometry of the reaction shows that 1 mole of \( H_2XO_4 \) produces 2 moles of H⁺. Therefore, the moles of \( H_2XO_4 \) can be calculated as: \[ \text{Moles of } H_2XO_4 = \frac{2.56 \times 10^{-3}}{2} = 1.28 \times 10^{-3} \, \text{moles} \] 5. **Find Molar Mass of \( H_2XO_4 \)**: - We know the mass of \( H_2XO_4 \) is \( 0.1254 \, \text{g} \). The molar mass (M) can be calculated using the formula: \[ M = \frac{\text{mass}}{\text{moles}} = \frac{0.1254 \, \text{g}}{1.28 \times 10^{-3} \, \text{moles}} \approx 97.96 \, \text{g/mol} \] 6. **Set Up the Equation for Molar Mass**: - The molar mass of \( H_2XO_4 \) can be expressed as: \[ 2 \times 1 + x + 4 \times 16 = 98 \] - Simplifying gives: \[ 2 + x + 64 = 98 \implies x + 66 = 98 \implies x = 32 \, \text{g/mol} \] - Here, \( x \) is the molar mass of the non-metal X. 7. **Identify the Non-Metal X**: - The atomic mass of 32 g/mol corresponds to sulfur (S), which has an atomic number of 16. 8. **Calculate the Number of Neutrons**: - The number of neutrons can be calculated using the formula: \[ \text{Number of Neutrons} = \text{Mass Number} - \text{Atomic Number} \] - For sulfur: \[ \text{Mass Number} = 32, \quad \text{Atomic Number} = 16 \] - Therefore: \[ \text{Number of Neutrons} = 32 - 16 = 16 \] ### Final Answer: The number of neutrons in X is **16**.
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