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Mole fraction of solvent in 0.2 m binary...

Mole fraction of solvent in 0.2 m binary aqueous solution of camphor (m = molality) is :

A

0.996

B

0.004

C

0.96

D

0.976

Text Solution

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The correct Answer is:
To find the mole fraction of the solvent in a 0.2 m binary aqueous solution of camphor, we will follow these steps: ### Step 1: Understand the given information We are given a 0.2 m (molality) solution of camphor (C10H16O). This means there are 0.2 moles of camphor in 1 kg of solvent (which is water in this case). ### Step 2: Calculate the number of moles of water The molar mass of water (H2O) can be calculated as follows: - Hydrogen (H) has an atomic mass of approximately 1 g/mol. Since there are 2 hydrogen atoms, their total mass is \(2 \times 1 = 2\) g/mol. - Oxygen (O) has an atomic mass of approximately 16 g/mol. - Therefore, the molar mass of water is \(2 + 16 = 18\) g/mol. Now, we can calculate the number of moles of water in 1 kg (1000 g): \[ \text{Number of moles of water} = \frac{\text{mass of water}}{\text{molar mass of water}} = \frac{1000 \text{ g}}{18 \text{ g/mol}} \approx 55.56 \text{ moles} \] ### Step 3: Calculate the total number of moles in the solution We have: - Moles of camphor = 0.2 moles - Moles of water = approximately 55.56 moles Total moles in the solution: \[ \text{Total moles} = \text{moles of water} + \text{moles of camphor} = 55.56 + 0.2 = 55.76 \text{ moles} \] ### Step 4: Calculate the mole fraction of the solvent (water) The mole fraction of the solvent (water) can be calculated using the formula: \[ \text{Mole fraction of solvent} = \frac{\text{moles of solvent}}{\text{total moles in solution}} = \frac{\text{moles of water}}{\text{total moles}} = \frac{55.56}{55.76} \] Calculating this gives: \[ \text{Mole fraction of solvent} \approx 0.9964 \] ### Step 5: Conclusion The mole fraction of the solvent (water) in the solution is approximately 0.9964. ### Final Answer: The mole fraction of the solvent in the 0.2 m binary aqueous solution of camphor is **0.9964**. ---
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