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The enolic form of acetone (CH(3)-overse...

The enolic form of acetone `(CH_(3)-overset(OH)overset(|)C=CH_2)` contains

A

`10 sigma`-bonds, `1pi` bond and 1 lone pair

B

`8sigma`-bonds , `2pi`-bonds and 2 lone pairs

C

`9sigma`bonds , `1pi` bond and 2 lone pairs

D

`9sigma` bonds, `2pi` bonds and 1 lone pair

Text Solution

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The correct Answer is:
To determine the number of sigma bonds, pi bonds, and lone pairs in the enolic form of acetone, which is represented as CH₃-C(OH)=CH₂, we can follow these steps: ### Step 1: Identify the Structure The enolic form of acetone can be represented as: ``` H H \ / C / \ H C | O | H ``` This structure shows that we have two carbon atoms (C) connected by a double bond, and one of the carbons is also connected to a hydroxyl group (OH). ### Step 2: Count Sigma Bonds 1. **C-H Bonds**: Each carbon (C) in the structure is bonded to hydrogen (H) atoms. - The first carbon (C1) is connected to three hydrogen atoms (C-H bonds). - The second carbon (C2) is connected to two hydrogen atoms (C-H bonds). Total C-H bonds = 3 (from C1) + 2 (from C2) = 5 sigma bonds. 2. **C-C Bond**: The two carbon atoms are connected by a single bond (C-C). - This is 1 sigma bond. 3. **C-O Bond**: The carbon (C2) is connected to the oxygen (O) in the hydroxyl group (OH). - This is also a sigma bond. Adding these together: - Total sigma bonds = 5 (C-H) + 1 (C-C) + 1 (C-O) = **7 sigma bonds**. ### Step 3: Count Pi Bonds - The double bond between the two carbon atoms (C1 and C2) consists of one sigma bond and one pi bond. - Therefore, there is **1 pi bond**. ### Step 4: Count Lone Pairs - The oxygen atom in the hydroxyl group (OH) has two lone pairs of electrons. - The carbon atoms do not have any lone pairs. Thus, the total number of lone pairs = **2 lone pairs** (from the oxygen atom). ### Final Summary - **Sigma bonds**: 7 - **Pi bonds**: 1 - **Lone pairs**: 2
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