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In the 500 ml flask following reaction t...

In the 500 ml flask following reaction takes place `H_(2)(g)+I_(2)(g)hArr 2HI(g)`. At equilibrium, concentration of `H_(2),I_(2) and HI` is 3, 2 and 1.5 mole then the value of `K_(C)` will be

A

3.75

B

0.375

C

3.25

D

0.187

Text Solution

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The correct Answer is:
To find the equilibrium constant \( K_C \) for the reaction \[ H_2(g) + I_2(g) \rightleftharpoons 2HI(g) \] given the concentrations at equilibrium, we follow these steps: ### Step 1: Write the expression for \( K_C \) The equilibrium constant \( K_C \) is defined as: \[ K_C = \frac{[HI]^2}{[H_2][I_2]} \] ### Step 2: Determine the concentrations of the reactants and products We are given the number of moles of each substance at equilibrium and the volume of the flask. The volume of the flask is 500 mL, which is equivalent to 0.5 L. - For \( H_2 \): 3 moles - For \( I_2 \): 2 moles - For \( HI \): 1.5 moles Now, we can calculate the concentrations: \[ [H_2] = \frac{3 \text{ moles}}{0.5 \text{ L}} = 6 \text{ M} \] \[ [I_2] = \frac{2 \text{ moles}}{0.5 \text{ L}} = 4 \text{ M} \] \[ [HI] = \frac{1.5 \text{ moles}}{0.5 \text{ L}} = 3 \text{ M} \] ### Step 3: Substitute the concentrations into the \( K_C \) expression Now we substitute the concentrations into the \( K_C \) expression: \[ K_C = \frac{[HI]^2}{[H_2][I_2]} = \frac{(3)^2}{(6)(4)} \] ### Step 4: Calculate \( K_C \) Calculating the values: \[ K_C = \frac{9}{24} = 0.375 \] ### Final Answer Thus, the value of \( K_C \) is: \[ K_C = 0.375 \]
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